| Identification | More | [Name]
2-(4-Bromophenyl)pyriding | [CAS]
63996-36-1 | [Synonyms]
2-(4-BROMOPHENYL)PYRIDINE
2-(4-Bromophenyl)pyriding | [Molecular Formula]
C11H8BrN | [MDL Number]
MFCD04116231 | [Molecular Weight]
234.09 | [MOL File]
63996-36-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
61.0 to 65.0 °C | [Boiling point ]
322.3±17.0 °C(Predicted) | [density ]
1.426±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Toluene | [form ]
powder to crystal | [pka]
4.29±0.25(Predicted) | [color ]
White to Light yellow to Light orange | [InChI]
InChI=1S/C11H8BrN/c12-10-6-4-9(5-7-10)11-3-1-2-8-13-11/h1-8H | [InChIKey]
FBQFCXDBCPREBP-UHFFFAOYSA-N | [SMILES]
C1(C2=CC=C(Br)C=C2)=NC=CC=C1 | [CAS DataBase Reference]
63996-36-1(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white solid powder | [Synthesis]
2-(4-Bromophenyl)pyriding can be synthesized via Suzuki coupling (e.g., reaction of 2-bromopyridine with 4-bromophenylboronic acid under palladium catalysis) to yield a white solid . | [Uses]
2-(4-Bromophenyl)pyriding serves as a precursor for the synthesis of cyclopalladated and cyclometalated iridium complexes[1]. 2-(4-Bromophenyl)pyriding is used in cyclopalladation reactions with 1 equivalent of Li2PdCl4 and NaOAc in methanol at room temperature for 12 h to prepare new cyclometalated palladium and iridium complexes[1]. | [References]
[1] Xu, C., Li, H.-M., Xiao, Z.-Q., Wang, Z.-Q., Tang, S.-F., Ji, B.-M., Hao, X.-Q., & Song, M.-P. (2014). Cyclometalated Pd(ii) and Ir(iii) 2-(4-bromophenyl)pyridine complexes with N-heterocyclic carbenes (NHCs) and acetylacetonate (acac): synthesis, structures, luminescent properties and application in one-pot oxidation/Suzuki coupling of aryl chlorides containing hydroxymethyl. Dalton Transactions, 26, 10235–10247. https://doi.org/10.1039/C4DT00833B
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| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956 |
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https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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Adamas Reagent, Ltd.
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4006009262 13023226327 |
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http://www.tansoole.com |
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