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66470-81-3

66470-81-3 Structure

66470-81-3 Structure
IdentificationBack Directory
[Name]

TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE
[CAS]

66470-81-3
[Synonyms]

tris(2h-perfluoro-2-propyl) phosphite
TRIS(1,1,1,3,3,3-HEXAFLUORO-2-PROPYL) PHOSPHITE
Tris(1,1,1,3,3,3-hexafluoro-2-propoxy)phosphite
Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite 98%
2-Propanol, 1,1,1,3,3,3-hexafluoro-, 2,2',2''-phosphite
Tris[2,2,2-trifluoro-1-(trifluoromethyl)ethyl] phosphite
Phosphorous Acid Tris(1,1,1,3,3,3-hexafluoro-2-propyl) Ester
phosphorous acid tris(1,1,1,3,3,3-hexafluoropropan-2-yl) ester
[Molecular Formula]

C9H3F18O3P
[MDL Number]

MFCD00192561
[MOL File]

66470-81-3.mol
[Molecular Weight]

532.06
Chemical PropertiesBack Directory
[Boiling point ]

130 °C(lit.)
[density ]

1.69 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.300(lit.)
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[BRN ]

2315565
[InChI]

1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H
[InChIKey]

MJOVEPJSFHDSOJ-UHFFFAOYSA-N
[SMILES]

FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[HS Code ]

2920290090
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) Phosphite acts as a catalyst in combination with rhodium complex in the hydroformylation of olefins.
[General Description]

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand. It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3. It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.
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