| Identification | More | [Name]
Diisopropyl phosphite | [CAS]
1809-20-7 | [Synonyms]
3P-230
DI-I-PROPYLPHOSPHITE
DIISOPROPYL HYDROGEN PHOSPHITE
DIISOPROPYL PHOSPHITE
DIISOPROPYL PHOSPHONATE
PHOSPHONIC ACID DIISOPROPYL ESTER
PHOSPHOROUS ACID DIISOPROPYL ESTER
Diisopropyl hydrogen phosphonate
Diisopropylphosphine oxide
Isopropyl phosphonate
Isopropyl phosphonate ((C3H7O)2HPO)
isopropylphosphonate
O,O-Diisopropyl phosphonate
o,o-diisopropylphosphite
o,o-diisopropylphosphonate
Phosphonic acid, bis(1-methylethyl) ester
phosphonicacid,bis(1-methylethyl)ester
Diipropylphosphitemincolorlessliq
Di-i-propylphosphite,min.98%
Dipropan-2-yl hydrogen phosphite | [EINECS(EC#)]
217-317-7 | [Molecular Formula]
C6H15O3P | [MDL Number]
MFCD00117905 | [Molecular Weight]
166.16 | [MOL File]
1809-20-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless liquid | [Boiling point ]
71 °C (8 mmHg)
| [density ]
0.997
| [refractive index ]
1.4065-1.4085
| [Fp ]
69°C | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Sparingly), Methanol (Sparingly) | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1 | [Water Solubility ]
soluble | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C6H15O3P/c1-5(2)8-10(7)9-6(3)4/h5-6,10H,1-4H3 | [InChIKey]
BLKXLEPPVDUHBY-UHFFFAOYSA-N | [SMILES]
P(=O)(OC(C)C)OC(C)C | [CAS DataBase Reference]
1809-20-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Phosphonic acid, di-isopropyl ester(1809-20-7) | [EPA Substance Registry System]
1809-20-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
3265 | [RTECS ]
SZ7660000 | [TSCA ]
Yes | [HS Code ]
29209085 | [Toxicity]
guinea pig,LC50,inhalation,9010mg/m3 (9010mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGESGASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDSBEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 29(11), Pg. 51, 1985. |
| Hazard Information | Back Directory | [Chemical Properties]
clear colourless liquid | [Uses]
Diisopropyl phosphite can be used as antiwear lubricant additive together with triphenyl thiophosphate on T8 steel/Al2O3 ceramics.
| [Preparation]
Diisopropyl phosphite is prepared by directly reacting isopropanol with phosphorus trichloride.
3(CH3)2CHOH+PCl3→[(CH3)2CHO]2POH+2HCl↑+(CH3)2CHCl
At a ratio of 3:1 (mol), continuously feed 215kg/h of isopropanol and 150kg/h of phosphorus trichloride. When mixed, this results in a violent reaction that generates hydrogen chloride gas. This gas is quickly removed from the mixing pot using vacuum mercury. The crude ester produced is then heated in a falling film type spinner deacidification device and further deacidified. The resulting product is then cooled to below 40°C and obtained with a content of 92%-95% and a yield of 95%～98%. | [Synthesis Reference(s)]
Tetrahedron Letters, 29, p. 3327, 1988 DOI: 10.1016/0040-4039(88)85153-0 |
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