ChemicalBook--->CAS DataBase List--->67564-91-4

67564-91-4

67564-91-4 Structure

67564-91-4 Structure
IdentificationBack Directory
[Name]

Fenpropimorph
[CAS]

67564-91-4
[Synonyms]

Corbel[R]
Mistral[R]
fenpropimorf
Fenpropimorph
Einecs 266-719-9
cis-fenpropimorph
Fenpropimorph cis-form
FENPROPIMORPH PESTANAL 250 MG
Fenpropimorph(100ug/mlinToluene)
2,6-dimethyl-4-[2-methyl-3-(4-tert-butylphenyl)-propyl]-morpholine
cis-4-(3-(p-tert-Butylphenyl)-2-methylpropyl)-2,6-dimethylmorpholin
cis-4-[3-(4-tert-Butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine
cis-4-[3-(p-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine
2,6-dimethyl-4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-morpholinc
cis-2,6-dimethyl-4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)morpholin
cis-4-[3-[4-(1,1-DiMethylethyl)phenyl]-2-Methylpropyl]-2,6-diMethylMorpholine
(2β,6β)-4-[3-[4-(1,1-Dimethylethyl)phenyl]-2-methylpropyl]-2,6-dimethylmorpholine
fenpropimorph cis-4-[3-(p-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine
cis-4-(3-(4-(1,1-Dimethylethyl)phenyl)-2-methylpropyl)-2,6-dimethylmorpholine (9ci)
(2R,6S)-rel-4-[3-[4-(1,1-DiMethylethyl)phenyl]-2-Methylpropyl]-2,6-diMethylMorpholine
Morpholine, 4-3-4-(1,1-dimethylethyl)phenyl-2-methylpropyl-2,6-dimethyl-, (2R,6S)-rel-
[EINECS(EC#)]

266-719-9
[Molecular Formula]

C20H33NO
[MDL Number]

MFCD00144306
[MOL File]

67564-91-4.mol
[Molecular Weight]

303.482
Chemical PropertiesBack Directory
[Melting point ]

25°C
[Boiling point ]

444.4°C (rough estimate)
[density ]

0.9804 (rough estimate)
[vapor pressure ]

0.004Pa at 20℃
[refractive index ]

1.5614 (estimate)
[Fp ]

>100 °C
[storage temp. ]

Store at -20°C
[solubility ]

DMF: 15 mg/ml,DMSO: 5 mg/ml,Ethanol: 15 mg/ml,Ethanol:PBS (pH 7.2)(1:2): 0.3 mg/ml
[form ]

A neat oil
[pka]

7.34±0.10(Predicted)
[Appearance]

Colorless to light yellow Liquid
[Water Solubility ]

4.32mg/L at 20℃
[Merck ]

13,4021
[Henry's Law Constant]

6.2×100 mol/(m3Pa) at 25℃, Mackay et al. (2006)
[Major Application]

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care
[InChI]

1S/C20H33NO/c1-15(12-21-13-16(2)22-17(3)14-21)11-18-7-9-19(10-8-18)20(4,5)6/h7-10,15-17H,11-14H2,1-6H3
[InChIKey]

RYAUSSKQMZRMAI-UHFFFAOYSA-N
[SMILES]

CC(CN1CC(C)OC(C)C1)Cc2ccc(cc2)C(C)(C)C
[LogP]

4.930
[EPA Substance Registry System]

Fenpropimorph (67564-91-4)
Hazard InformationBack Directory
[Uses]

Systemic fungicide for control of powdery mildew, rust in cereal crops.
[Definition]

ChEBI: (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine is an alkylbenzene.
[Production Methods]

Fenpropimorph is commercially produced through multi-step organic synthesis, starting with morpholine derivatives that are chemically modified to introduce functional groups essential for its fungicidal activity. The process typically involves alkylation and cyclization reactions to form the morpholine ring system, followed by the addition of phenyl and propyl substituents to create the active compound.
[Flammability and Explosibility]

Notclassified
[Mechanism of action]

Systemic with protective and curative action. Disrupts membrane function.
[Pesticide Type]

Fungicide
Safety DataBack Directory
[Hazard Codes ]

Xn;N,N,Xn
[Risk Statements ]

22-38-51/53-63
[Safety Statements ]

36/37-46-61
[RIDADR ]

UN 3082
[WGK Germany ]

WGK 3
[RTECS ]

QE1940000
[REACH Registrations]

Active
[HS Code ]

29349990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 2
Repr. 2
Skin Irrit. 2
Questions And AnswerBack Directory
[Description]

Fenpropimorph is a morpholine fungicide. It is colorless, odorless oil.
Fenpropimorph, a systemic fungicide, absorbed through the leaves and roots, has protective and curative properties. It can inhibit the sterol pathway. It is mostly used for the control of fungal diseases, including powdery mildew, scald, yellow & brown rusts, and Mycosphaerella. Its is major use is to control diseases in cereals including wheat, barley, oats, rye, and triticale. It could be also applied on bananas, plantains, sugarbeet and beans.
[References]

[1] http://sitem.herts.ac.uk/aeru/ppdb/en/Reports/308.htm
[2] Kalyani Paranjape, Vasant Gowariker, V N Krishnamurthy, Sugha Gowariker (2013) The Pesticide Encyclopedia
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