| Identification | Back Directory | [Name]
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& | [CAS]
677736-23-1 | [Synonyms]
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& ISO 9001：2015 REACH
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium
Dicarbonylchloro[(1,2,3,4,5,-η:)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium | [Molecular Formula]
C35H25.2CO.ClRu | [MDL Number]
MFCD09265041 | [MOL File]
677736-23-1.mol | [Molecular Weight]
638.125 |
| Chemical Properties | Back Directory | [Melting point ]
152-167 °C | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
solid | [Appearance]
Light yellow to yellow Solid | [InChIKey]
NGSBLRJKXUHTOC-UHFFFAOYSA-M | [SMILES]
[C]1([C](C2C=CC=CC=2)[C]([C](C2C=CC=CC=2)[C]1C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[O+]#[C-].[O+]#[C-].[Ru]Cl |^1:0,1,8,9,16| |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
- Ligand exchange
- Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds
Catalyst for:
- (S)-Selective dynamic kinetic resolution of secondary alcohols
- Stereoselective synthesis of neonicorinoide pesticide derivatives
- Divergent asymmetric synthesis of 3,5-disubstituted piperidines
| [reaction suitability]
core: ruthenium
reagent type: catalyst |
|
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|