| Identification | Back Directory | [Name]
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) | [CAS]
578743-87-0 | [Synonyms]
[(iPr)CuCl]
Chloro[1,3-bis(2,6-diisopropylphenyl)iMidazol-2-ylidene]copp
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper chloride
CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)
Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I)
Chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I),98%
[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) chloride
(1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium-2-yl) copper chloride
[1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene](chloro)copper | [Molecular Formula]
C27H36ClCuN2 *- | [MDL Number]
MFCD09264276 | [MOL File]
578743-87-0.mol | [Molecular Weight]
487.587 |
| Chemical Properties | Back Directory | [Melting point ]
>300 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
white | [Sensitive ]
air sensitive | [InChI]
InChI=1S/C27H36N2.ClH.Cu/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;1H;/q;;+1/p-1 | [InChIKey]
JPUFNIIPFXQOCB-UHFFFAOYSA-M | [SMILES]
N1(C=CN(C2C(=CC=CC=2C(C)C)C(C)C)C1=[Cu]Cl)C1=C(C=CC=C1C(C)C)C(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the aziridination of olefins.
- Mild catalyst, superior to CuCl, in the methylenetriphenylphosphorane methyleneation of aldehydes and ketones.
- Copper(I) catalyzed alkylation of aryl and alkenylsilanes.
- Copper-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide.
- Regioselective copper-catalyzed carboxylation of allylboronates with carbon dioxide.
- Carboxylation of organoboronic esters with potassium methyl carbonate under copper catalysis.
- Catalytic anti-Markovnikov hydrobromination of alkynes.
- Copper-catalyzed borylative cross-coupling of allenes and imines.
|
| Hazard Information | Back Directory | [Uses]
"Use for reduction of olefin and carbonyl, carbene transfer reaction, aziridination of olefins, and methyleneation of aldehydes." | [reaction suitability]
core: copper
reagent type: catalyst |
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
T&W GROUP
|
| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
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