| Identification | Back Directory | [Name]
BOC-D-TYR(ME)-OH | [CAS]
68856-96-2 | [Synonyms]
BOC-D-TYR(ME)-OH
BOC-D-4-METHOXYPHE
BOC-D-PHE(4-OME)-OH
BOC-L-PHE(4-OCH3)-OH
BOC-D-TYROSINE(ME)-OH
BOC-P-METHOXY-D-PHE-OH
Boc-π-methoxy-D-Phe-OH
Boc-4-methoxy-D-Phe-OH
BOC-O-METHYL-D-TYROSINE
N-Boc-O-methyl-D-tyrosine
BOC-D-TYR(ME)-OH USP/EP/BP
N-ALPHA-T-BOC-O-METHYL-D-TYROSINE
(Tert-Butoxy)Carbonyl D-Tyr(Me)-OH
Boc-O-methyl-D-tyrosine≥ 98% (HPLC)
N-Boc-4-Methoxy-D-phenylalanine, 95%
N-ALPHA-T-BOC-P-METHOXY-D-PHENYLALANINE
N-ALPHA-T-BUTOXYCARBONYL-O-METHYL-D-TYROSINE
N-alpha-t-butoxycarbonyl-o-nethyl-D-tyrosine
N-(tert-Butoxycarbonyl)-D-4-methoxyphenylalanine
N-(tert-Butoxycarbonyl)-4-methoxy-D-phenylalanine
N-ALPHA-T-BUTOXYCARBONYL-4-METHOXY-D-PHENYLALANINE
D-Tyrosine,N-[(1,1-dimethylethoxy)carbonyl]-O-methyl-
(R)-2-TERT-BUTOXYCARBONYLAMINO-3-(4-METHOXY-PHENYL)-PROPIONIC ACID
(R)-2-((tert-butoxycarbonyl)aMino)-3-(4-Methoxyphenyl)propanoic acid
(2R)-3-(4-methoxyphenyl)-2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoicaci
(2R)-3-(4-methoxyphenyl)-2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid | [Molecular Formula]
C15H21NO5 | [MDL Number]
MFCD00065604 | [MOL File]
68856-96-2.mol | [Molecular Weight]
295.33 |
| Chemical Properties | Back Directory | [Melting point ]
93.0 to 97.0 °C | [Boiling point ]
462.0±40.0 °C(Predicted) | [density ]
1.168±0.06 g/cm3(Predicted) | [storage temp. ]
Store at 0-5°C | [form ]
powder to crystal | [pka]
3.00±0.10(Predicted) | [color ]
White to Almost white | [Optical Rotation]
Consistent with structure |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Boc-O-methyl-D-tyrosine is a compound involved in the design and synthesis of β-sheet-based self-assembling cyclic peptides with tunable cavities. | [Synthesis]
General procedure for the synthesis of N-Boc-4-methoxy-D-phenylalanine from methyl (S)-2-((tert-butoxycarbonyl)amino)-3-(4-methoxyphenyl)propionate: in the presence of 1 mL of water, K2CO3 (0.089 g, 0.608 mmol) was added to a (S)-2-((tert-butoxycarbonyl)amino)-3-(4-methoxyphenyl) Methyl propionate (0.100 g, 0.323 mmol) was added to a solution in methanol (4 mL). The reaction mixture was stirred at room temperature for 12 hours. After completion of the reaction, methanol was removed by rotary evaporation. The reaction mixture was diluted with water and the aqueous layer was extracted with ethyl acetate. The organic layers were combined, dried with anhydrous Na2SO4, filtered and concentrated under reduced pressure. The crude product was purified by column chromatography using ethyl acetate and petroleum ether (1:1) as eluent to give pure N-Boc-4-methoxy-D-phenylalanine. | [References]
[1] Tetrahedron Letters, 2012, vol. 53, # 52, p. 7128 - 7130
[2] Journal of Organic Chemistry, 1981, vol. 46, # 9, p. 1944 - 1946
[3] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 19, p. 5607 - 5612 |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Shanghai GL Peptide Ltd.
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+86-21-61263310 13764994101 |
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