| Identification | More | [Name]
3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE | [CAS]
707-61-9 | [Synonyms]
2,3-DIHYDRO-4-METHYL-1-PHENYL-1H-PHOSPHOLE 1-OXIDE
3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE
3-METHYL-1-PHENYL-2-PHOSPHOLENE OXIDE
4-METHYL-1-PHENYL-2,3-DIHYDRO-1H-1LAMBDA5-PHOSPHOL-1-ONE
4-METHYL-1-PHENYL-2,3-DIHYDROPHOSPHOL-1-ONE
1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide
1H-Phosphole,2,3-dihydro-4-methyl-1-phenyl-,1-oxide
2,3-dihydro-4-methyl-1-phenyl-1h-phosphol1-oxide
2-Phospholene, 3-methyl-1-phenyl-, 1-oxide
3-methyl-1-phenyl-2-phospholen1-oxide
3-Methyl-1-Phenyl-2-Phosphelene 1-Oxide
3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE TECH., 85%
4,5-Dihydro-3-Methyl-1-Phenylphosphole1-Oxide
3-Methyl-1-phenyl-2-phospholene-1-oxide, ca. 98%
4,5-Dihydro-3-Methyl-1-Phenyl-Oxo-Pentylidene Phosphine
1-Methyl-3-phenyl-2-phospholene 1-oxide
1-Phenyl-3-methyl-4,5-dihydro-1H-phosphole 1-oxide
1-Phenyl-4-methyl-2,3-dihydro-1H-phosphole 1-oxide
3-Methyl-1-phenyl-4,5-dihydro-1H-phosphole 1-oxide
4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide | [EINECS(EC#)]
211-901-5 | [Molecular Formula]
C11H13OP | [MDL Number]
MFCD00014518 | [Molecular Weight]
192.19 | [MOL File]
707-61-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white to yellow adhering crystals | [Melting point ]
58-62 °C
| [Boiling point ]
150 °C/0.15 mmHg (lit.) | [density ]
1.11±0.1 g/cm3(Predicted) | [refractive index ]
n20/D 1.5707(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Soluble in polar solvents. | [form ]
Lumps | [color ]
White to cream | [Sensitive ]
Hygroscopic | [BRN ]
609223 | [InChI]
InChI=1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3 | [InChIKey]
YMKWWHFRGALXLE-UHFFFAOYSA-N | [SMILES]
P1(=O)(C2=CC=CC=C2)C=C(C)CC1 | [CAS DataBase Reference]
707-61-9(CAS DataBase Reference) | [EPA Substance Registry System]
1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide (707-61-9) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS08 | [Signal word ]
Warning | [Hazard statements ]
H302-H351-H412 | [Precautionary statements ]
P201-P273-P301+P312+P330-P308+P313 | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [WGK Germany ]
3
| [RTECS ]
SZ6105100
| [TSCA ]
Yes | [HS Code ]
2931499090 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Chronic 3
Carc. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
white to yellow adhering crystals | [Uses]
3-Methyl-1-phenyl-2-phospholene 1-oxide is used as a catalyst for intramolecular aza-wittig cyclization reactions and polymerization reactions. It is a reactant used for the preparation of phospha sugars and their radical bromination derivatives as anticancer agents. | [Application]
Catalyst for:
Intramolecular aza-Wittig cyclization reactions
Polymerization reactions
Reactant for preparation of:
Phospha sugars and their radical bromination derivatives as anticancer agents | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|