| Identification | More | [Name]
Trichlorovinylsilane | [CAS]
75-94-5 | [Synonyms]
(TRICHLOROSILYL)ETHYLENE
TRICHLOROVINYLSILANE
VINYLTRICHLOROSILANE
VTC
A 150
a150
a150(silane)
CH2=CHSiCl3
CV-4900
Dynasylan VTC
Silane, ethenyl trichloro-
Silane, trichlorovinyl-
Silane, Vinyltrichloro-
Silane, vinyltrichloro A-150
Silane,trichloroethenyl-
silane,vinyltrichloroa-150
Trichloro(ethenyl)silane
trichloroethenyl-silan
trichloroethenyl-Silane
Trichlorovinyl silicane | [EINECS(EC#)]
200-917-8 | [Molecular Formula]
C2H3Cl3Si | [MDL Number]
MFCD00000482 | [Molecular Weight]
161.49 | [MOL File]
75-94-5.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless or pale-yellow liquid. Readily hydrolyzed with
liberation of hydrogen chloride; polymerizes easily;
soluble in most organic solvents; reacts with
alcohol. | [Melting point ]
−95 °C(lit.) | [Boiling point ]
90 °C(lit.) | [density ]
1.27 g/mL at 25 °C(lit.)
| [vapor density ]
>1 (vs air)
| [vapor pressure ]
60 mm Hg ( 23 °C)
| [refractive index ]
n20/D 1.436(lit.)
| [Fp ]
51 °F
| [storage temp. ]
0-6°C | [form ]
liquid | [color ]
colorless | [Specific Gravity]
1.27 | [Water Solubility ]
reacts | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [BRN ]
1743440 | [InChI]
1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2 | [InChIKey]
GQIUQDDJKHLHTB-UHFFFAOYSA-N | [SMILES]
Cl[Si](Cl)(Cl)C=C | [CAS DataBase Reference]
75-94-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Silane, (trichloro)ethenyl-(75-94-5) | [EPA Substance Registry System]
75-94-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R14:Reacts violently with water.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R20:Harmful by inhalation. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S8:Keep container dry .
S30:Never add water to this product .
S29:Do not empty into drains . | [RIDADR ]
UN 1305 3/PG 1
| [WGK Germany ]
1
| [RTECS ]
VV6125000
| [F ]
21 | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
I | [HS Code ]
29319090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1A | [Safety Profile]
Moderately toxic by
ingestion, inhalation, and sktn contact. A
corrosive irritant to skin, eyes, and mucous
membranes. A very dangerous fire hazard
when exposed to heat or flame. Reacts
violently with water, moist air, or steam to
produce toxic and corrosive fumes. When
heated to decomposition it emits toxic
fumes of Cl-. See also CHLOROSILANES. | [Hazardous Substances Data]
75-94-5(Hazardous Substances Data) | [Toxicity]
LD50 oral in rat: 1280mg/kg |
| Hazard Information | Back Directory | [Reactivity Profile]
Chlorosilanes, such as VINYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. | [Health Hazard]
Inhalation causes irritation of mucous membranes. Vapor irritates eyes. Contact with liquid causes severe burns of eyes and skin. Ingestion causes burns of mouth and stomach. | [Chemical Properties]
Colorless or pale-yellow liquid. Readily hydrolyzed with
liberation of hydrogen chloride; polymerizes easily;
soluble in most organic solvents; reacts with
alcohol. | [Uses]
Trichlorovinylsilane is used to Intermediate for silicones, coupling agent in adhesives and bonds. A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane. | [General Description]
Vinyltrichlorosilane appears as a colorless to pale yellow fuming liquid with a pungent odor. Vapor and liquid may cause burns. More dense than water. Vapors are heavier than air. | [Purification Methods]
Fractionally distil it at atmospheric pressure. It is water sensitive and is stored in the dark and it is likely to polymerise. [Müller & Schnurrbusch Chem Ber 91 1805 1958, Munkelt & Müller Chem Ber 92 1012 1959, Polarography: Abrahamson & Reynolds Anal Chem 24 1827 1952, Beilstein 4 IV 4258.] | [Toxics Screening Level]
The initial threshold screening level (ITSL) for antimony is 7 μg/m3 (annual averaging time). |
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