| Identification | More | [Name]
ALLYLTRIPHENYLTIN | [CAS]
76-63-1 | [Synonyms]
ALLYLTRIPHENYLTIN
TINALLYLTRIPHENYL
TRIPHENYLALLYLTIN
allyltriphenyl-stannan
allyltriphenylstannane
dowco187
ent50909
triphenyl-2-propenyl-stannan
Allyltriphenyltin,97%
2-propenyl-triphenylstannane
2-Propenyl-triphenylstannane, Allyltriphenyltin
3-(Triphenylstannyl)-1-propene
Triphenyl(2-propenyl)stannane
Triphenyl(allyl)stannane
Triphenylallyltin(IV) | [EINECS(EC#)]
200-975-4 | [Molecular Formula]
C21H20Sn | [MDL Number]
MFCD00048162 | [Molecular Weight]
391.09 | [MOL File]
76-63-1.mol |
| Chemical Properties | Back Directory | [Appearance]
Needle-like crystals from alc.Sol in most org solvs.
| [Melting point ]
71-74 °C(lit.) | [Boiling point ]
421.4±38.0 °C(Predicted) | [density ]
1,07 g/cm3 | [Fp ]
>100 | [Water Solubility ]
Insoluble in water | [form ]
solid | [color ]
White to Almost white | [Hydrolytic Sensitivity]
1: no significant reaction with aqueous systems | [BRN ]
3612762 | [CAS DataBase Reference]
76-63-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3146 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
WH6705000
| [TSCA ]
No | [HS Code ]
2931.90.6000 | [HazardClass ]
6.1(b) | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Hazard]
A poison. | [Chemical Properties]
Needle-like crystals from alc.Sol in most org solvs.
| [Uses]
Allyltriphenylstannane can be used:
- As a reagent in the C-H phenylation of azoles catalyzed by palladium.
- As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)3.
- As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.
| [General Description]
Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals. |
|
| Company Name: |
INTATRADE GmbH
|
| Tel: |
+49 3493/605464 |
| Website: |
www.intatrade.de |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|