ChemicalBook--->CAS DataBase List--->766-49-4

766-49-4

766-49-4 Structure

766-49-4 Structure
IdentificationMore
[Name]

1-ETHYNYL-2-FLUOROBENZENE
[CAS]

766-49-4
[Synonyms]

1-ETHYNYL-2-FLUOROBENZENE
2'-FLUOROPHENYL ACETYLENE
2-FLUOROPHENYLACETYLENE
Benzene, 1-ethynyl-2-fluoro-(7CI, 8CI, 9CI)
[Molecular Formula]

C8H5F
[MDL Number]

MFCD00799540
[Molecular Weight]

120.12
[MOL File]

766-49-4.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow to brownish liquid
[Boiling point ]

150 °C (lit.)
[density ]

1.06 g/mL at 25 °C(lit.)
[refractive index ]

1.524-1.527
[Fp ]

37 °C
[storage temp. ]

Refrigerator (+4°C)
[form ]

Liquid
[color ]

Clear yellow to brownish
[CAS DataBase Reference]

766-49-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R10:Flammable.
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29039990
Hazard InformationBack Directory
[Chemical Properties]

clear yellow to brownish liquid
[Uses]

1-Ethynyl-2-fluorobenzene has been employed in the cross-coupling of phenylacetylenes. It may be used in the preparation of 3-(2-deoxy-β-D-ribofuranosyl)-6-(2-fluorophenyl)-2,3-dihydrofuro-[2,3-d]pyrimidin-2-one and 4-(2-fluorophenylethynyl)-3-methyl-5-phenylisoxazole.
[Uses]

Employed in studies on the polymerization1 and cross-coupling2 of phenylacetylenes.
[Application]

1-Ethynyl-2-fluorobenzene has been employed in the cross-coupling of phenylacetylenes. It may be used in the preparation of 3-(2-deoxy-β-D-ribofuranosyl)-6-(2-fluorophenyl)-2,3-dihydrofuro-[2,3-d]pyrimidin-2-one and 4-(2-fluorophenylethynyl)-3-methyl-5-phenylisoxazole.1-Ethynyl-2-fluorobenzene, a fluorinated benzene derivative, is a terminal alkyne.
[General Description]

1-Ethynyl-2-fluorobenzene, a fluorinated benzene derivative, is a terminal alkyne.
Spectrum DetailBack Directory
[Spectrum Detail]

1-ETHYNYL-2-FLUOROBENZENE(766-49-4)MS
1-ETHYNYL-2-FLUOROBENZENE(766-49-4)1HNMR
1-ETHYNYL-2-FLUOROBENZENE(766-49-4)13CNMR
1-ETHYNYL-2-FLUOROBENZENE(766-49-4)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Ethynyl-2-fluorobenzene, 97%(766-49-4)
[Sigma Aldrich]

766-49-4(sigmaaldrich)
[TCI AMERICA]

1-Ethynyl-2-fluorobenzene,>97.0%(GC)(766-49-4)
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