ChemicalBook--->CAS DataBase List--->7779-77-3

7779-77-3

7779-77-3 Structure

7779-77-3 Structure
IdentificationMore
[Name]

Isobutyl anthranilate
[CAS]

7779-77-3
[Synonyms]

FEMA 2182
ISOBUTYL ANTHRANILATE
2-amino-benzoicaci2-methylpropylester
Benzoicacid,2-amino-,2-methylpropylester
isobutylb10361anthranilate
2-amino-benzoic acid 2-methylpropyl ester
2-Methylpropyl 2-aminobenzoate
Anthranilic acid isobutyl
o-Aminobenzoic acid isobutyl ester
[EINECS(EC#)]

231-938-0
[Molecular Formula]

C11H15NO2
[MDL Number]

MFCD00053630
[Molecular Weight]

193.24
[MOL File]

7779-77-3.mol
Chemical PropertiesBack Directory
[Appearance]

brown liquid
[Boiling point ]

118 °C
[density ]

1,06 g/cm3
[FEMA ]

2182
[pka]

2.10±0.10(Predicted)
[Odor]

at 100.00 %. grape sweet fruity floral berry
[Stability:]

Stable, but air and light sensitive. Combustible. Hydrolyses under acidic or basic conditions.
[Odor Type]

fruity
[JECFA Number]

1537
[LogP]

3.45
[CAS DataBase Reference]

7779-77-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzoic acid, 2-amino-, 2-methylpropyl ester(7779-77-3)
[EPA Substance Registry System]

7779-77-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[TSCA ]

TSCA listed
[HazardClass ]

IRRITANT
Hazard InformationBack Directory
[General Description]

Brown liquid. Insoluble in water.
[Reactivity Profile]

ISOBUTYL ANTHRANILATE(7779-77-3) hydrolyzes under acidic or basic conditions.
[Air & Water Reactions]

This compound is sensitive to air and light. Insoluble in water.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits toxic fumes.
[Fire Hazard]

Flash point data for this compound are not available. ISOBUTYL ANTHRANILATE is probably combustible.
[Description]

Isobutyl anthranilate has a faint, orange flowers odor. Prepared by heating the anhydride of N-carboxyl anthranilic acid with sodium isobutoxide and subsequently hydrolyzing the reaction product.
[Chemical Properties]

brown liquid
[Application]

Isobutyl anthranilate is an interesting modifier in Jasmin, Neroli and Orangeblossom fragrances, and lends tenacity, sweetness and richness to many types of floral or Oriental fragrances. It is used quite extensively in flavor compositions, not only in the traditional Grape (American type) and Mandarin, but also in Cherry, Pineapple, Strawberry, Raspberry imitation flavors. Concentrations are up to 12 or 14 ppm in the finished product, except in chewing gum where it may reach 1700 ppm.
[Definition]

ChEBI: 2-Methylpropyl 2-aminobenzoate is a benzoate ester.
[Production Methods]

Isobutyl anthranilate can be produced by direct esterification of iso-Butylalcohol with Anthranilic acid under azeotropic conditions, or from Isatoic anhydride by reaction with e.g. Aluminium iso-Butoxide in iso-butylalcoholic solution.
Questions And AnswerBack Directory
[Aroma]

Renounced fruity, very sweet and deep (warm) odor, yet fresh and with only a faintly floral undertone.
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