ChemicalBook--->CAS DataBase List--->78119-82-1

78119-82-1

78119-82-1 Structure

78119-82-1 Structure
IdentificationMore
[Name]

6-Hydroxy-2-naphthaldehyde
[CAS]

78119-82-1
[Synonyms]

6-HYDROXY-2-NAPHTHALDEHYDE
2-Hydroxy-6-Naphthaldehyde
6-Hydroxy-2-naphthaldehyde 95%
6-HYDROXY-2-NAPHTHALDEHYDE, 99+%
2-Naphthol-6-carboxaldehyde
[Molecular Formula]

C11H8O2
[MDL Number]

MFCD03427537
[Molecular Weight]

172.18
[MOL File]

78119-82-1.mol
Chemical PropertiesBack Directory
[Melting point ]

178-180
[Boiling point ]

373.4±15.0 °C(Predicted)
[density ]

1.288±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Solid
[pka]

8.60±0.40(Predicted)
[Appearance]

White to off-white Solid
[InChI]

InChI=1S/C11H8O2/c12-7-8-1-2-10-6-11(13)4-3-9(10)5-8/h1-7,13H
[InChIKey]

PRYNJOJHKYNLIS-UHFFFAOYSA-N
[SMILES]

C1=C2C(C=C(O)C=C2)=CC=C1C=O
[CAS DataBase Reference]

78119-82-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

52
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

2912490090
Spectrum DetailBack Directory
[Spectrum Detail]

6-Hydroxy-2-naphthaldehyde(78119-82-1)1HNMR
6-Hydroxy-2-naphthaldehyde(78119-82-1)FT-IR
Well-known Reagent Company Product InformationBack Directory
[TCI AMERICA]

6-Hydroxy-2-naphthaldehyde,>98.0%(GC)(T)(78119-82-1)
Hazard InformationBack Directory
[Synthesis]

A stirring bar, 0.35 g (2.01 mmol) of 6-hydroxy-2-naphthylcarbinol and 20 mL of N, N-dimethylformamide were introduced into a 100 mL flask to form a homogenous mixture. This mixture was added with 3.5 g (36.94 mmol) of electrolytic manganese dioxide (FMH, Tosoh, purity: 91.77 per cent) and vigorously stirred for 16 hours while the mixture was maintained at 20°C. The reaction mixture was analyzed by using liquid chromatography. As a result, it was found that the conversion of the 6-hydroxy-2-naphthylcarbinol was 92.3 per cent, and the yield of the 6-hydroxy-2-naphthaldehyde was 87 percent.
[References]

[1] Patent: CN105111054, 2017, B. Location in patent: Paragraph 0088; 0089; 0090
[2] Patent: WO2006/82245, 2006, A1. Location in patent: Page/Page column 156
[3] Patent: US2003/229120, 2003, A1. Location in patent: Page 52
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