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8006-75-5

8006-75-5 Structure

8006-75-5 Structure
IdentificationBack Directory
[Name]

Dill Oil
[CAS]

8006-75-5
[Synonyms]

DILL OIL
oilofdill
Oils,dill
FEMA 2383
anethioil
dillfruitoil
DILLWEED OIL
DILL HERB OIL
dilloilindian
OIL, DILLWEED
DILL SEED OIL
Dill seeqd oil
DILLWEED OIL FCC
DILLWEED OLEORESIN
Anethum Gravolens
Dillseedoil/CH5293
dillseedoil,indian
dillseedoileuropean
americandillweedoil
Dillseedoil/CH85547
Dillseedoil/CH70229
Dillseedoil/CH77140
Dillseedoil/CH68611
Dillseedoil/CH48758
Dillseedoil/CH80661
Dillseedoil/CH79614
Dillseedoil/CH47229
Dillseedoil/CH67901
Dilloil,seed/Carvones
anethumgraveolens,oil
DILL OIL, AMERICAN TYPE
DILLWEED OIL, AMERICAN TYPE
DILL HERB OIL, AMERICAN TYPE
DILL (ANETHUM GRAVEOLENS L.)
DILLWEEDOIL,AMERICANTYPE,FCC
DILL SEED INDIAN (ANETHUM SPP.)
DILL OIL (ANETHUM GRAVEOLENS L.)
[EINECS(EC#)]

289-790-8
[MDL Number]

MFCD00240704
Chemical PropertiesBack Directory
[Boiling point ]

189 °C(lit.)
[density ]

0.888 g/mL at 25 °C
[FEMA ]

2383 | DILL OIL (ANETHUM GRAVEOLENS L.)
[refractive index ]

n20/D 1.483(lit.)
[Fp ]

147 °F
[Odor]

at 100.00 %. dill
[Odor Type]

herbal
[optical activity]

[α]20/D +90°, neat
[EPA Substance Registry System]

Oils, dill(8006-75-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

38-10
[Safety Statements ]

37-16
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

2
[RTECS ]

RJ3691500
[Safety Profile]

Mildly toxic by ingestion. A skin irritant. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes.
[Toxicity]

The acute oral LD50 value in rats was reported as 4.04 ml/kg and the acute dermal LD50 value in rabbits as > 5 g/kg (Levenstein, 1975).
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

p-Anisaldehyde-->D(+)-Carvone
Hazard InformationBack Directory
[Chemical Properties]

Dill weed oil, which is the most important, is obtained by steam distillation of the dill weed (herb) before the fruits becomemature. Itsmain constituents are ??-phellandrene (10–20%), limonene (30–40%), carvone (30–40%), and the so-called (+)-dill ether (up to 10%). The latter is responsible for the typical organoleptic properties of the dill plant and, thus, of dill weed oil. Annually, ~150 t are produced mainly in the United States and Canada, smaller quantities come from Eastern Europe (Bulgaria, Hungary, Ukraine).
[Chemical Properties]

In North America, there are two forms of dill encountered: Dill weed oil (A. graveolens) and Dill seed oil (A. sowa Robx.) (usually of Indian origin). Dill seed oil is also separately described under Dill Indian (see). (1) Dill weed oil: In the United States, the essential oil is obtained by steam distillation of the fresh herb (stalks, leaves and seeds). American dill weed has a strong, fresh, somewhat spicy, aromatic odor and a warm, slightly burning taste. (2) Dill seed oil: Dill seed oil is obtained by steam distillation of the fruits (seeds). The oil has a caraway-like odor and flavor because of the higher carvone content as compared to dill weed oil.
[Physical properties]

Dill weed oil: American dill weed oil is a pale-yellow to yellow liquid. Dill seed oil: The oil is a slightly yellow liquid.
[Occurrence]

Found in the plant of A . graveolens, L. (Fam. Umbelliferae) (Guenther, 1950).
[Definition]

Extractives and their physically modified derivatives. Anethum graveolens, Umbelliferae.
[Preparation]

By steam distillation of the freshly cut plants of A . graveolens L. (Guenther, 1950).
[Essential oil composition]

Dill seed oil: Limonene (5.9%), α-pinene (1.3%), γ-terpinene (0.1%), decanal (0.2%), terpinen-4-ol (0.1%), β-elemene (0.1%), cis-dihydrocarvone and caryophyllene (0.8%), trans-hydrocarone (16.6%), carvone (20.9%), dillapiole (52.5%).
Dill weed oil: The major constituents are carvone (35%), limonene (25%), α-phellandrene (29%), 3,7-dimethyl-4,5,6,7-tetrahydrocoumaran (2.9%). In addition, myristicin, dillapiole and unidentified waxes have been reported.
[Pharmacology]

Dill oil from parts of the A . graveolens plant at concentrations of 50-100 μg/ml had a spasmolytic effect on smooth muscle (isolated rabbit and guinea-pig intestine and guinea-pig lung) and a 5% emulsion in physiological saline given iv to cats at 5-10 mg/kg increased respiratory volume and depressed blood pressure (Shipochliev, 1968). The spasmolytic effect was considered to be chiefly myotropic.
In nearly 100 haemorrhoidal patients, one-third of whom were young, repeated oral doses and nightly enemas of an aqueous infusion prepared from 20-25 g dill plant (A. graveolens) in 200-250 g water caused complete and lasting reduction of venous knots in 2-3 wk (Freise, 1938).
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