| Identification | More | [Name]
1-NITROANTHRAQUINONE | [CAS]
82-34-8 | [Synonyms]
1-NITROANTHRAQUINONE
1-Nitoanthrapuinone
1-nitro-10-anthracenedione
1-Nitro-9,10-anthracenedione
1-nitroanthrachinon
1-nitro-anthraquinon
alpha-nitroanthraquinone
Nitroanthraquinone
1-nitroanthracene-9,10-dione
1-Nitro-9,10-anthraquinone | [EINECS(EC#)]
201-413-0 | [Molecular Formula]
C14H7NO4 | [MDL Number]
MFCD00019140 | [Molecular Weight]
253.21 | [MOL File]
82-34-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Yellow needles from AcOH;yellow
plates by sublimation; soluble in EtOH and Et2O;
slightly soluble in EtOAc, benzene and CHCl3;
insoluble in water. | [Melting point ]
232.5~233.5℃ | [Boiling point ]
270~271℃(933Pa) | [density ]
1.3146 (rough estimate) | [refractive index ]
1.4700 (estimate) | [Fp ]
243.3 ±18.5 ℃ | [storage temp. ]
Sealed in dry,Room Temperature | [Water Solubility ]
Insoluble in water | [form ]
powder to crystal | [color ]
Light yellow to Brown | [InChI]
InChI=1S/C14H7NO4/c16-13-8-4-1-2-5-9(8)14(17)12-10(13)6-3-7-11(12)15(18)19/h1-7H | [InChIKey]
YCANAXVBJKNANM-UHFFFAOYSA-N | [SMILES]
C1([N+]([O-])=O)=C2C(C(=O)C3=C(C2=O)C=CC=C3)=CC=C1 | [CAS DataBase Reference]
82-34-8(CAS DataBase Reference) | [EPA Substance Registry System]
9,10-Anthracenedione, 1-nitro- (82-34-8) |
| Safety Data | Back Directory | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S22:Do not breathe dust .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RTECS ]
CB7940000 | [TSCA ]
TSCA listed | [HS Code ]
2914.69.9000 |
| Hazard Information | Back Directory | [Hazard]
Hepatotoxic; moderately toxic; may cause
hepatocellular neoplasms, subcutaneous fibromas,
subcutaneous hemangiosarcomas, and type II pneumocyte proliferation. | [Chemical Properties]
Yellow needles from AcOH;yellow
plates by sublimation; soluble in EtOH and Et2O;
slightly soluble in EtOAc, benzene and CHCl3;
insoluble in water. | [Uses]
1-Nitroanthraquinone is used in the manufacture of various dyes, pharmaceuticals and similar products, either directly or after reduction to l-aminoanthraquinone. | [Synthesis Reference(s)]
Tetrahedron Letters, 16, p. 1429, 1975 DOI: 10.1016/S0040-4039(00)72160-5 | [Synthesis]
1-Nitroanthraquinone is prepared by nitration of
anthraquinone in nitric acid (danger of explosion!)
, sulfuric acid , organic
solvents , phosphoric acid , or hydrogen
fluoride .
Purification from organic solvents by addition
of bases, such as amines , alcoholates
, or hydrazine , or from water by
addition of sodium sulfite . 1-Nitroanthraquinone
is crystallized from nitric acid ,
from organic solvents, for example, nitrobenzene
, or from amides . The resulting
1-nitroanthraquinone may be finally purified by
high-temperature distillation , . |
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