| Identification | Back Directory | [Name]
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE | [CAS]
828927-94-2 | [Synonyms]
(R,S)-O-PINAP
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine,Min.95%(R,S)-O-PINAP
(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP | [Molecular Formula]
C38H29N2OP | [MDL Number]
MFCD11973799 | [MOL File]
828927-94-2.mol | [Molecular Weight]
560.634 |
| Chemical Properties | Back Directory | [Melting point ]
178-181°C | [alpha ]
-160.4° (c 0.53, CHCl3) | [Boiling point ]
726.4±60.0 °C(Predicted) | [form ]
crystal | [pka]
3.45±0.30(Predicted) | [color ]
colorless | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reaction]
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
- With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
- With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
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