828927-95-3

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828927-95-3 Structure

Identification	Back Directory
[Name] (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
[CAS] 828927-95-3
[Synonyms] (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
[Molecular Formula] C38H29N2OP
[MDL Number] MFCD11973799

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H302-H315-H319-H335
[Precautionary statements ] P261-P280-P301+P312-P302+P352-P305+P351+P338

[Reaction]

The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.

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