Identification | Back Directory | [Name]
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP | [CAS]
828927-95-3 | [Synonyms]
(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP | [Molecular Formula]
C38H29N2OP | [MDL Number]
MFCD11973799 |
Questions And Answer | Back Directory | [Reaction]
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
- With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
- With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
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