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828927-95-3

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828927-95-3 Structure

828927-95-3 Structure
IdentificationBack Directory
[Name]

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
[CAS]

828927-95-3
[Synonyms]

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,R)-O-PINAP
[Molecular Formula]

C38H29N2OP
[MDL Number]

MFCD11973799
Chemical PropertiesBack Directory
[Melting point ]

64-65°C
[alpha ]

+78.5° (c 0.25, CHCl3)
[form ]

crystal
[color ]

colorless
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
Questions And AnswerBack Directory
[Reaction]

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777,15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
  2. With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
  3. With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
Reactions of 828927-95-3
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