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832-69-9

832-69-9 Structure

832-69-9 Structure
IdentificationBack Directory
[Name]

1-METHYLPHENANTHRENE
[CAS]

832-69-9
[EINECS(EC#)]

212-622-1
[Molecular Formula]

C15H12
[MDL Number]

MFCD00058942
[MOL File]

832-69-9.mol
[Molecular Weight]

192.26
Chemical PropertiesBack Directory
[Melting point ]

123°C
[Boiling point ]

353.25°C (rough estimate)
[density ]

1.0561 (estimate)
[refractive index ]

1.6031 (estimate)
[solubility ]

Soluble in alcohol (Weast, 1986)
[color ]

White powder or solid.
[Henry's Law Constant]

1.56, 2.33, 3.42, 4.93, and 6.68 x 10-5 atm?m3/mol at 4.1, 11.0, 18.0, 25.0, and 31.0 °C, respectively (Bamford et al., 1998)
Hazard InformationBack Directory
[Definition]

ChEBI: A member of the class of phenanthrenes that is phenanthrene substituted by a methyl group at position 1.
[General Description]

White crystalline powder.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1-METHYLPHENANTHRENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction. 1-METHYLPHENANTHRENE is sensitive to excessive heat and light.
[Fire Hazard]

Flash point data for 1-METHYLPHENANTHRENE are not available. 1-METHYLPHENANTHRENE is probably combustible.
[Source]

Detected in 8 diesel fuels at concentrations ranging from 0.10 to 210 mg/L with a mean value of 44.33 mg/L (Westerholm and Li, 1994). Identified in a South Louisiana crude oil at a concentration of 111 ppm (Pancirov and Brown, 1975). Schauer et al. (1999) reported 1- methylphenanthrene in diesel fuel at a concentration of 28 μg/g and in a diesel-powered mediumduty truck exhaust at an emission rate of 17.0 μg/km.
California Phase II reformulated gasoline contained 1-methylphenathrene at a concentration of 3.91 g/kg. Gas-phase tailpipe emission rates from gasoline-powered automobiles with and without catalytic converters were approximately 1.63 and 122 μg/km, respectively (Schauer et al., 2002).
Schauer et al. (2001) measured organic compound emission rates for volatile organic compounds, gas-phase semi-volatile organic compounds, and particle-phase organic compounds from the residential (fireplace) combustion of pine, oak, and eucalyptus. The respective gas-phase and particle-phase emission rates of 1-methylphenanthrene were 2.22 and 0.579 mg/kg of pine burned and 1.04 and 0.050 mg/kg of oak burned. The gas-phase emission rate was 0.720 mg/kg of eucalyptus burned.
Spectrum DetailBack Directory
[Spectrum Detail]

1-METHYLPHENANTHRENE(832-69-9)MS
1-METHYLPHENANTHRENE(832-69-9)1HNMR
1-METHYLPHENANTHRENE(832-69-9)13CNMR
1-METHYLPHENANTHRENE(832-69-9)IR1
1-METHYLPHENANTHRENE(832-69-9)IR2
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