| Identification | More | [Name]
4-Nitrodiphenylamine | [CAS]
836-30-6 | [Synonyms]
4-NITRODIPHENYLAMINE
4-NITRO-N-PHENYLANILINE
(4-NITROPHENYL)PHENYLAMINE
LABOTEST-BB LT01487848
P-NITRODIPHENYLAMINE
TIMTEC-BB SBB008055
4-ndpa
4-Nitrodifenylamin
4-nitrodifenylamin(czech)
4-nitro-diphenylamin
4-nitro-n-phenyl-benzenamin
4-nitro-n-phenylbenzenamine
4-nitro-N-phenyl-benzenamine
Benzenamine, 4-nitro-N-phenyl-
diphenyl,4-nitro-amin
Diphenylamine, 4-nitro-
N-(4-Nitrophenyl)-N-phenylamine
p-Nitrophenylphenylamine
4-Nitrodiphenylamine, 98+%
ANILINE,4-NITRO-N-PHENYL | [EINECS(EC#)]
212-646-2 | [Molecular Formula]
C12H10N2O2 | [MDL Number]
MFCD00007301 | [Molecular Weight]
214.22 | [MOL File]
836-30-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Orange Crystalline Solid | [Melting point ]
132-135 °C (lit.) | [Boiling point ]
211 °C (30 mmHg)
| [density ]
1.2042 (rough estimate) | [refractive index ]
1.6660 (estimate) | [Fp ]
190°C | [storage temp. ]
Refrigerator | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
-2.60±0.20(Predicted) | [color ]
Orange to Brown | [Water Solubility ]
INSOLUBLE | [BRN ]
2051910 | [InChI]
1S/C12H10N2O2/c15-14(16)12-8-6-11(7-9-12)13-10-4-2-1-3-5-10/h1-9,13H | [InChIKey]
XXYMSQQCBUKFHE-UHFFFAOYSA-N | [SMILES]
[O-][N+](=O)c1ccc(Nc2ccccc2)cc1 | [CAS DataBase Reference]
836-30-6(CAS DataBase Reference) | [NIST Chemistry Reference]
N-(4-Nitrophenyl)-N-phenylamine(836-30-6) | [EPA Substance Registry System]
836-30-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
3077 | [WGK Germany ]
3
| [RTECS ]
JJ9600000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29214400 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Hazardous Substances Data]
836-30-6(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Chemical Properties]
Orange Crystalline Solid | [Uses]
4-Nitrodiphenylamine was used to study reduction of nitrated diphenylamine derivatives in sediment water batch enrichments and dense cell suspensions of anaerobic, aromatic-compound-mineralizing pure bacterial cultures. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 42, p. 1786, 1977 DOI: 10.1021/jo00430a025 | [General Description]
4-Nitrodiphenylamine undergoes heterogeneous catalytic transfer hydrogenation to form p-phenylenediamines. 4-Nitrodiphenylamine is used as stabilizer for propellants and explosives. | [Purification Methods]
Crystallise the amine from EtOH or aqueous EtOH (m 135-136o) and has m 131.5-132o after sublimation in vacuo. [Beilstein 12 H 715, 12 III 1586.] | [Toxics Screening Level]
The NOEL from this study was reported as 8.5 mg/m3. The calculation for the
ITSL of 1 μg/m3 on an annually averaged basis |
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