| Identification | Back Directory | [Name]
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL | [CAS]
84783-64-2 | [Synonyms]
BIPHEP
98% BIPHEP
2,2'-Bis(diphenylphosphino)-1
2,2'-Bis(diphenylphosphino)bip
2,2'-BIS(DIPHENYLPHOSPHINO)BIPHENYL
2,2’-Bis(diphenylphospino)-1,1’-biphenyl
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%
2,2'-Bis(diphenylphosphino)-1,1'-biphenyl
2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP
2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP)
{2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane
1,1'-[[1,1'-Biphenyl]-2,2'-diyl]bis[1,1-diphenylphosphine]
PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL- | [Molecular Formula]
C36H28P2 | [MDL Number]
MFCD03094574 | [MOL File]
84783-64-2.mol | [Molecular Weight]
522.56 |
| Chemical Properties | Back Directory | [Appearance]
white crystalline powder or crystals | [Melting point ]
210-214 °C
| [Boiling point ]
635.5±48.0 °C(Predicted) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [solubility ]
soluble in Toluene | [form ]
crystal | [color ]
white | [InChI]
1S/C36H28P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H | [InChIKey]
GRTJBNJOHNTQBO-UHFFFAOYSA-N | [SMILES]
c1ccc(cc1)P(c2ccccc2)c3ccccc3-c4ccccc4P(c5ccccc5)c6ccccc6 |
| Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder or crystals | [Uses]
2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
| Questions And Answer | Back Directory | [Reaction]
- Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
- Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
- Useful ligand for palladium-catalyzed synthesis of butatrenes.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
- Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
- Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
- Ruthenium-catalyzed synthesis of indoles.
- Ruthenium-catalyzed oxidative cyclization.
- Rhodium-catalyzed boron arylation.
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