| Identification | Back Directory | [Name]
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE | [CAS]
85417-41-0 | [Synonyms]
TDMPP
Tris(2,6-dimethoxyphenly)phosphine
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Tris(2,6-dimethoxyphenyl)phosphine 98%
Tris(2,6-dimethoxyphenyl)phosphine, 97+%
Tris(2,6-diMethoxyphenyl)phosphine, 97+% 5GR
TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE 97+% HPLC
Tris(2,6-dimethoxyphenyl)phosphine, min. 97% | [Molecular Formula]
C24H27O6P | [MDL Number]
MFCD00192558 | [MOL File]
85417-41-0.mol | [Molecular Weight]
442.44 |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
145-147 °C(lit.)
| [Boiling point ]
566.4±50.0 °C(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
very faint turbidity in hot Methanol | [form ]
Powder | [color ]
white to off-white | [Sensitive ]
air sensitive | [InChI]
1S/C24H27O6P/c1-25-16-10-7-11-17(26-2)22(16)31(23-18(27-3)12-8-13-19(23)28-4)24-20(29-5)14-9-15-21(24)30-6/h7-15H,1-6H3 | [InChIKey]
CMLWFCUAXGSMBB-UHFFFAOYSA-N | [SMILES]
COc1cccc(OC)c1P(c2c(OC)cccc2OC)c3c(OC)cccc3OC | [CAS DataBase Reference]
85417-41-0 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Catalyst for:
- Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
- Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
- Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
- Oxycylizations of allendiols
- Enantioselective aldol reactions
- Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
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