| Identification | More | [Name]
TRIS(3-METHOXYPHENYL)PHOSPHINE | [CAS]
29949-84-6 | [Synonyms]
TRIS(3-METHOXYPHENYL)PHOSPHINE
TRIS(M-ANISYL)PHOSPHINE
TRIS(M-METHOXYPHENYL)PHOSPHINE
Phosphine,tris(3-methoxyphenyl)-
Trismmethoxyphenylphosphinewhitextl
TRIS(3-METHOXYPHENYL)PHOSPHINE 97%
Tris(m-methoxyphenyl)phosphine,97+%
tri(m-anisyl)phosphine | [EINECS(EC#)]
631-150-0 | [Molecular Formula]
C21H21O3P | [MDL Number]
MFCD00008386 | [Molecular Weight]
352.36 | [MOL File]
29949-84-6.mol |
| Chemical Properties | Back Directory | [Appearance]
White to almost white crystalline powder | [Melting point ]
113-115 °C(lit.) | [Boiling point ]
476.3±40.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Crystalline Powder | [color ]
White to almost white | [InChI]
InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3 | [InChIKey]
CCXTYQMZVYIQRP-UHFFFAOYSA-N | [SMILES]
P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1 | [CAS DataBase Reference]
29949-84-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P280a-P304+P340-P305+P351+P338-P405-P501a | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29310099 |
| Hazard Information | Back Directory | [Chemical Properties]
White to almost white crystalline powder | [Uses]
suzuki reaction | [Synthesis]
1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1?mmol NaPH2, 2?mol?% PF6, 11?equiv 1-iodo-3-methoxybenzene, 15?equiv Et3N in 2.0?mL MeCN under blue LED irradiation and N2 atmosphere for 24?h[1].
 | [References]
[1]"Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight." Angewandte Chemie (2021). |
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