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856405-77-1

856405-77-1 Structure

856405-77-1 Structure
IdentificationBack Directory
[Name]

9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS
[CAS]

856405-77-1
[Synonyms]

97% t-Bu-XANTPHOS
9,9-Dimethyl-4,5-bis(di-tert-butylphosphino)xanthene 97%
4,5-Bis[di(tert-butyl)phosphino]-9,9-dimethyl-9H-xanthene
9,9-Dimethyl-4,5-bis(di-t-butylphosphino)xanthene, min. 97%
(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis(di-tert-butylphosphine)
9,9-DiMethyl-4,5-bis(di-t-butylphosphino)xanthene,97% t-Bu-XANTPHOS
9,9-DiMethyl-4,5-bis(di-t-butylphosphino)xanthene, 99% t-Bu-XANTPHOS
9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS
Phosphine, (9,9-dimethyl-9H-xanthene-4,5-diyl)bis[bis(1,1-dimethylethyl)-
[Molecular Formula]

C31H48OP2
[MDL Number]

MFCD07781995
[MOL File]

856405-77-1.mol
[Molecular Weight]

498.66
Chemical PropertiesBack Directory
[Melting point ]

153-157℃
[Boiling point ]

563.1±50.0 °C(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

white to light yellow
[CAS DataBase Reference]

856405-77-1
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37
[WGK Germany ]

3
[TSCA ]

No
Questions And AnswerBack Directory
[Reactions]

  • Ligand used in the cobalt-catalyzed alkenylzincation of unfunctionalized alkynes.
  • Ligand used in the cobalt-catalyzed alkylboration of alkenes.
  • Ligand used in the palladium-catalyzed N-alkylation of amines using primary and secondary alcohols.
  • Ligand used in the palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides
Reactions of 856405-77-1
Spectrum DetailBack Directory
[Spectrum Detail]

9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS(856405-77-1)1HNMR
9,9-DIMETHYL-4,5-BIS(DI-T-BUTYLPHOSPHINO)XANTHENE, MIN. 97% T-BU-XANTPHOS(856405-77-1)31PNMR
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