| Identification | Back Directory | [Name]
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP | [CAS]
856407-37-9 | [Synonyms]
(R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane
(11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin
4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP | [Molecular Formula]
C25H23P | [MDL Number]
MFCD17018763 | [MOL File]
856407-37-9.mol | [Molecular Weight]
354.424 |
| Chemical Properties | Back Directory | [Melting point ]
148-149°C | [alpha ]
+6° (c 0.5, CH2Cl2) | [Boiling point ]
505.6±50.0 °C(Predicted) | [form ]
solid | [color ]
white | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reaction]
- Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
- Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
- Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
- Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.
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