| Identification | Back Directory | [Name]
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) | [CAS]
887919-35-9 | [Synonyms]
Pd(amphos)Cl2
PdCl2(Amphos)2
(A-taPhos)2PdCl2
Bis(di-tert-butyl(4-diMethyl
Pd(aMphos)Cl2, 15% Pd, Product of UMicore
Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…
Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline)
Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine)palladium(11)
Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II)
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II)
Bis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]dichloropalladiuM, 95%
Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride
Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II), Pd 15%
Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II), Pd 15%
Bis[(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine] palladiuM(II) chloride
palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride
Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98%
BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) PdCl2(AMphos)2
Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
(SP-4-1)-Palladium dichloro-bis[4-[bis(1,1-dimethylethyl)phosphino-P]-N,N-dimethylbenzenamine]
Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)-
Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}dichloropalladium(II), Bis{4-[bis(tert-butyl)phosphanyl]-N,N-dimethylaniline}dichloropalladium(II) | [EINECS(EC#)]
1308068-626-2 | [Molecular Formula]
2C16H28NP.Cl2Pd | [MDL Number]
MFCD09265123 | [MOL File]
887919-35-9.mol | [Molecular Weight]
708.082 |
| Chemical Properties | Back Directory | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Powder | [color ]
yellow | [Water Solubility ]
Insoluble in water. | [InChI]
InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H; | [InChIKey]
AWOFSUFKCXRJMV-UHFFFAOYSA-N | [SMILES]
P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow powder | [Uses]
Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides | [reaction suitability]
reagent type: catalyst
reaction type: Cross Couplings | [Synthesis]
To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.
| [References]
[1] Patent: CN105237568, 2017, B. Location in patent: Paragraph 0064-0066 |
| Questions And Answer | Back Directory | [Reaction]
- Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
- Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.
|
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|