| Identification | Back Directory | [Name]
DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) | [CAS]
40691-33-6 | [Synonyms]
PdCl2[P(o-Tol)3]2
DICHLOROBIS(TRI-O-TOLYLPHOSPHI
DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
Dichlorobis(tri-o-tolylphsophine)palladium, 98%
Bis[tri(o-tolyl)phosphine]palladium(II) chloride
BIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) DICHLORIDE
TRANS-DICHLOROBIS-(TRI-O-TOLYLPHOSPHINE)-PALLADIUM
trans-Dichlorobis(tri-o-tolylphosphine)palladium(Ⅱ)
TRANS-DICHLOROBIS(TRI-O-TOLYL-PHOSPHINE)PALLADIUM(II)
PalladiuM,dichlorobis[tris(2-Methylphenyl)phosphine]-
bis(tris(2-methylphenyl)phosphane) palladium dichloride
trans-Dichlorobis(tri-ortho-tolylphosphine) palladium(Ⅱ)
Dichlorobis(tri-o-tolylphosphine)palladium(II), Pd 17.6%
palladiuM(2+) dichloride - tris(2-Methylphenyl)phosphane
trans-dichlorobis(tri-o-tolylphosphine)palladium(II)95+%
trans-Dichlorobis(tri-o-tolylphosphine)palladium(II),min.95%
palladiuM(2+) dichloride-tris(2-Methylphenyl)phosphane (1:2)
trans-Dichlorobis(tri-o-tolylphosphine)palladium(II), min. 95%
trans-Dichlorobis(tri-ortho-toylphosphine) palladium (II) ,95% [C%: 61.9 - 66.4 %] | [Molecular Formula]
C42H42Cl2P2Pd | [MDL Number]
MFCD00274659 | [MOL File]
40691-33-6.mol | [Molecular Weight]
786.06 |
| Chemical Properties | Back Directory | [Appearance]
Yellow to orange crystalline powder | [Melting point ]
280 °C (dec.)(lit.)
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Soluble in ethanol, benzene, and ethereal solvents. | [form ]
Crystalline Powder | [color ]
Yellow to orange | [Sensitive ]
Air & Moisture Sensitive | [InChI]
InChI=1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H; | [InChIKey]
KFQYTZDYGOBBOE-UHFFFAOYSA-N | [SMILES]
P(C1C=CC=CC=1C)(C1C=CC=CC=1C)(C1C=CC=CC=1C)[Pd+2]([Cl-])([Cl-])P(C1C=CC=CC=1C)(C1C=CC=CC=1C)C1C=CC=CC=1C |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow to orange crystalline powder | [Uses]
Coupling reaction of aryl bromides with vinylic acetates. | [Uses]
suzuki reaction | [General Description]
Dichlorobis(tri-o-tolylphosphine)palladium(II) is a useful catalyst for C-C and C-N coupling reactions. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium | [Synthesis]
Under the protection of argon, 15.5 g of tetrakis(triphenylphosphine)palladium(0) (Pd (PPh3) 4) (4 mmol), 7 mmol of p-bromotoluene, 0.5246 g of triphenylmercury (PPh3) (2 mmol) and 35 mL of toluene were added into a 100 mL Schlenk vial with electromagneti |
|
|