| Identification | More | [Name]
2-Benzoylpyridine | [CAS]
91-02-1 | [Synonyms]
2-BENZOYLPYRIDINE
AKOS 94378
AKOS B022444
PHENYL 2-PYRIDYL KETONE
PHENYL(PYRIDIN-2-YL)METHANONE
2-benzoyl-pyridin
2-pyridylphenylketone
Ketone, phenyl 2-pyridyl
ketone,phenyl2-pyridyl
Phenyl(2-pyridinyl)methanone
phenyl-2-pyridinyl-methanon
Pyridine, 2-benzoyl-
2-BENZOYLPYRIDINE, 99+%
Methanone, phenyl-2-pyridinyl-
Phenyl pyridin-2-yl ketone
BENZOYLPYRIDINE
Phenyl (2-pyridinyl) ketone | [EINECS(EC#)]
202-034-3 | [Molecular Formula]
C12H9NO | [MDL Number]
MFCD00006300 | [Molecular Weight]
183.21 | [MOL File]
91-02-1.mol |
| Chemical Properties | Back Directory | [Appearance]
COLOURLESS TO SLIGHTLY YELLOW CRYSTALLINE CHUNKS | [Melting point ]
41-43 °C (lit.) | [Boiling point ]
317 °C (lit.) | [density ]
1,556 g/cm3 | [refractive index ]
1.5880 (estimate) | [Fp ]
302 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Crystalline Chunks | [pka]
2.90±0.10(Predicted) | [color ]
Colorless to slightly yellow | [Water Solubility ]
insoluble | [BRN ]
120283 | [InChI]
1S/C12H9NO/c14-12(10-6-2-1-3-7-10)11-8-4-5-9-13-11/h1-9H | [InChIKey]
GCSHUYKULREZSJ-UHFFFAOYSA-N | [SMILES]
O=C(c1ccccc1)c2ccccn2 | [LogP]
1.880 | [Uses]
Organic synthesis. | [CAS DataBase Reference]
91-02-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Methanone, phenyl-2-pyridinyl-(91-02-1) | [EPA Substance Registry System]
91-02-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
OB6400000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29333999 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
COLOURLESS TO SLIGHTLY YELLOW CRYSTALLINE CHUNKS | [Synthesis Reference(s)]
Journal of Heterocyclic Chemistry, 24, p. 1061, 1987 DOI: 10.1002/jhet.5570240429
Tetrahedron Letters, 25, p. 1715, 1984 DOI: 10.1016/S0040-4039(01)81152-7 | [Purification Methods]
Dissolve 2-benzoylpyridine in Et2O, shake it with aqueous NaHCO3, H2O, dry it over MgSO4 and evaporate. The residue solidifies on cooling. The solid can be recrystallised from pet ether. Its hydrochloride crystallises from Me2CO, m 126-127o, and the 2,4-dinitrophenylhydrazone has m 193-195o. It distils at high vacuum. [Kinkerton & Thames J Organomet Chem 24 623 1970, Beilstein 21/8 V 566.] |
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