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915299-24-0

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915299-24-0 Structure

915299-24-0 Structure
IdentificationBack Directory
[Name]

[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
[CAS]

915299-24-0
[Synonyms]

Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
[Molecular Formula]

C42H64AuClO3P
[MDL Number]

MFCD11045473
[MOL File]

915299-24-0.mol
[Molecular Weight]

880.36
Chemical PropertiesBack Directory
[Melting point ]

200-202 °C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

powder
[InChIKey]

GCWCLHMEYZKZRO-UHFFFAOYSA-M
[SMILES]

Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Gold Catalysts — 21st Century ′Gold Rush′
  • Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes

Catalyst for:
  • [4C+2C] cycloadditions
  • Cis-selective single-cleavagte skeletal cycloisomerization
  • Diastereoselective Au-catalyzed intermolecular cyclopropanation
  • Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
  • Addition reactions
[reaction suitability]

core: gold
reagent type: catalyst
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