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26741-53-7

26741-53-7 Structure

26741-53-7 Structure
IdentificationMore
[Name]

Antioxidant 24
[CAS]

26741-53-7
[Synonyms]

3,9-bis(2,4-bis(1,1-dimethylethyl)phenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro(5.5)undecane
ADK Stab PEP 24
antioxidant 24
Bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite
mark pep 24
Ultranox 626
3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane
BIS-(2,4-DI-TERT-BUTYLPHENYL)PENTAERYTHRITOL DIPHOSPHITE (ULTRANOX 626)
2,4,8,10-Tetraoxa-3,9-diphosphaspiro5.5undecane, 3,9-bis2,4-bis(1,1-dimethylethyl)phenoxy-
3,9-Bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro(5.5)undecan
4,8,10-Tetraoxa-3,9-diphosphaspiro[5.5]undecane, 3,9-bis[2,4-bis(1,1-dimethylethyl)phenoxy]-2
phosphorous acid, cyclic neopentanetetrayl bis(2,4-di-tert-butylphenyl)ester
Bis-(2,4-di-tert-butylphenyl)-pentaerythrityl diphosphite
Alknox P-24(Great Lake)Ultranox 626(GE)
cyclic neopentanetetrayl bis(di-tert-butylphenyl)phosphite
Antioxidant AT-626
2,2'-Bis(2,4-di-tert-butylphenoxy)spiro[1,3,2-dioxaphosphorinane-5,5'-[1,3,2]dioxaphosphorinane]
Alkanox-P-24
[EINECS(EC#)]

247-952-5
[Molecular Formula]

C33H54O8P2
[MDL Number]

MFCD00071521
[Molecular Weight]

640.72
[MOL File]

26741-53-7.mol
Questions And AnswerBack Directory
[Appearance]

Ultranox 626 is a white powder or granule.  
[Application]

Antioxidant 626 (ultranox 626) is Approved by the FDA for food contact applications under 21CFRl78.2010 covering antioxidants and/or stabilizers for poly­mers.
[Features]

Ultranox 626 (Antioxidant 24, Irgafos 126) is suitable for polyolefins, polyesters, styrenes, engineering thermoplastics, PVC, elastomers and adhesives. Its products have excellent color stability, reduced polymer degradation, low dosage and higher phosphorus content than competitive phosphite antioxidants. It has synergistic effects when used with light stabilizers such as benzophenone and benzotriazole.
Chemical PropertiesBack Directory
[Melting point ]

160-178°C
[Boiling point ]

555.8±50.0 °C(Predicted)
[density ]

1.166[at 20℃]
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform (Slightly), Hexanes (Slightly, Heated)
[form ]

Solid
[color ]

White to Off-White
[Water Solubility ]

93μg/L at 25℃
[Stability:]

Hygroscopic
[InChIKey]

AIBRSVLEQRWAEG-UHFFFAOYSA-N
[SMILES]

C1C2(COP(OC3=CC=C(C(C)(C)C)C=C3C(C)(C)C)OC2)COP(OC2=CC=C(C(C)(C)C)C=C2C(C)(C)C)O1
[LogP]

10.9 at 25℃
[CAS DataBase Reference]

26741-53-7(CAS DataBase Reference)
[EPA Substance Registry System]

26741-53-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Environment (GHS09)
GHS09
[Signal word ]

Warning
[Hazard statements ]

H410
[Precautionary statements ]

P273-P391-P501
[TSCA ]

TSCA listed
[HS Code ]

2920.29.0000
[REACH Registrations]

Active
Hazard InformationBack Directory
[Description]

Antioxidant 626 is a white to off-white powdery substance with low volatility and higher efficiency. It is often used in combination with hindered phenolic antioxidants.
[Characteristics]

Excellent colour stability during compounding, fabrication and end-use.
Reduction in polymer degradation during processing.
Improved gas fading performance in many applications.
High performance at low loading levels for more cost-effective formulations.
Higher phosphorous content than competitive phosphite antioxidants.
Synergism when used with light stabilizers such as benzophenones and benzotriazoles.
[Uses]

Antioxidant 626 is suitable for: polyolefin and olefin copolymers, polycarbonate, polyamide and other engineering plastics, rubber and elastomers, coatings and adhesives.
[Definition]

Ultranox 626 is a solid organophosphite antioxidant that improves gas fading performance and color stability during compounding, fabrication, and end use. It delivers high performance at low loading rates, making this a cost-effective addition to polymer formulas. Ultranox 626 synergizes with benzophenone and benzotriazole light stabilizers. It is so effective that it can replace another phosphite antioxidant in your formula and deliver equivalent performance at a significantly lower dosing rate.
[Flammability and Explosibility]

Notclassified
[Synthesis]

2,4-Di-tert-butylphenol

96-76-4

3,9-dichloro-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane

3643-70-7

Ultranox 626

26741-53-7

(3) The product dichloropentaerythritol diphosphite obtained from step (2) was dropwise added to a 0.6 mol/L aqueous solution of 2,4-di-tert-butylphenol. The molar ratio of 2,4-di-tert-butylphenol to dichloropentaerythritol diphosphite was maintained at 2.30:1. The mixture was stirred under nitrogen at a speed of 800 rpm and reacted at 60°C for 2 hours. The hydrogen chloride gas generated during the reaction was absorbed by a sodium hydroxide solution. (4) The solvent was removed by vacuum distillation under reduced pressure at 100°C and 0.06 MPa. An appropriate amount of isopropanol was then added to the residue, and the mixture was stirred to crystallize the product. (5) The reaction mixture obtained from step (4) was subjected to suction filtration to yield a white solid powder, identified as bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite.

[References]

[1] Patent: CN108250240, 2018, A. Location in patent: Paragraph 0034; 0037; 0038; 0106; 0108; 0110; 0112; 0114
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