| Identification | More | [Name]
1,3-Diphenylbenzene | [CAS]
92-06-8 | [Synonyms]
1,3-DIPHENYLBENZENE M-DIPHENYLBENZENE 1,1':3',1-Terphenyl 1,1':3',1''-Terphenyl 1,1’:3’,1’’-biphenyl 1,1’:3’,1’’-Terphenyl 1,1'-Biphenyl, 3-phenyl- 1,3-Terphenyl 3-phenyl-1,1’-biphenyl 3-phenyl-1’-biphenyl 3-Phenylbiphenyl benzene,1,3-diphenyl- Isodiphenylbenzene m-terphenyle m-Triphenyl Santowax M santowaxm M-TERPHENYL OEKANAL, 250 MG m-Terphenyl,99% 3-TERPHENYL | [EINECS(EC#)]
202-122-1 | [Molecular Formula]
C18H14 | [MDL Number]
MFCD00003059 | [Molecular Weight]
230.3 | [MOL File]
92-06-8.mol |
| Chemical Properties | Back Directory | [Appearance]
Needles. | [Melting point ]
84-88 °C (lit.) | [Boiling point ]
379 °C (lit.) | [density ]
1,2 g/cm3 | [refractive index ]
1.5681 (estimate) | [Fp ]
191°C | [storage temp. ]
Store at room temperature | [form ]
neat | [color ]
White to Light yellow | [Water Solubility ]
1.511mg/L(25 ºC) | [BRN ]
1864778 | [Exposure limits]
NIOSH: IDLH 500 mg/m3; Ceiling 0.5 ppm(5 mg/m3) | [InChI]
InChI=1S/C18H14/c1-3-8-15(9-4-1)17-12-7-13-18(14-17)16-10-5-2-6-11-16/h1-14H | [InChIKey]
YJTKZCDBKVTVBY-UHFFFAOYSA-N | [SMILES]
C1(C2=CC=CC(C3=CC=CC=C3)=C2)=CC=CC=C1 | [CAS DataBase Reference]
92-06-8(CAS DataBase Reference) | [NIST Chemistry Reference]
m-Terphenyl(92-06-8) | [EPA Substance Registry System]
92-06-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S60:This material and/or its container must be disposed of as hazardous waste . | [OEL]
Ceiling: 5 mg/m3 (0.5 ppm) | [RIDADR ]
UN 3077 9/PG 3 | [WGK Germany ]
2
| [RTECS ]
WZ6470000
| [TSCA ]
Yes | [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29029090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Aquatic Acute 1 Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 | [Safety Profile]
Moderately toxic by ingestion. Combustible when exposed to heat or flame. To fight fire, use water, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. | [Hazardous Substances Data]
92-06-8(Hazardous Substances Data) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
1,5-diphenylpenta-1,4-diyn-3-ol-->Sulfur, [1,1'-biphenyl]-3-ylpentafluoro-, (OC-6-21)--->diphenyl(2,2,2-trifluoroethyl)sulfanium trifluoromethanesulfonate-->1,3-DIIODOBENZENE-->Biphenyl-3-boronic acid-->4-TOLUENESULFONYLACETONE-->3-Bromobiphenyl-->1,3-Dichlorobenzene-->1,3-Dibromobenzene-->Benzoylacetone | [Preparation Products]
branched polyphenylene-->3-CHLOROBIPHENYL-->1,3-Di(4-carboxyphenyl)benzene-->Biphenyl-->1,1':3',1''-Tercyclohexane |
| Hazard Information | Back Directory | [General Description]
Yellow solid. Mp 86-87°C; bp: 365°C. Density: 1.195 g cm-3. Insoluble in water. Usually shipped as a solid mixture with its isomers o-terphenyl and p-terphenyl that is used as a heat-transfer fluid. | [Reactivity Profile]
M-TERPHENYL is non-flammable but combustible (flash point 403°F). Extremely stable thermally. Incompatible with strong oxidizing agents but not very reactive at room conditions. | [Chemical Properties]
Needles. | [Uses]
m-Terphenyl is a polychlorinated terphenyl used in electronic equipments, lubricants, sealants and other devices. It is also found as a global environmental contaminant. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 51, p. 3162, 1986 DOI: 10.1021/jo00366a016 | [Hazard]
Moderately toxic by ingestion. Combustible.
Eye and upper respiratory tract irritant. | [Purification Methods]
Purify it as for o-terphenyl above. [Beilstein 5 IV 2480.] |
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