| Identification | More | [Name]
1,1-DIMETHOXYCYCLOHEXANE | [CAS]
933-40-4 | [Synonyms]
1,1-DIMETHOXYCYCLOHEXANE
CYCLOHEXANONE DIMETHYL ACETAL
CYCLOHEXANONE DIMETHYL KETAL
DIMETHOXYCYCLOHEXANE
TIMTEC-BB SBB008403 | [Molecular Formula]
C8H16O2 | [MDL Number]
MFCD00043714 | [Molecular Weight]
144.21 | [MOL File]
933-40-4.mol |
| Chemical Properties | Back Directory | [Boiling point ]
83 °C/50 mmHg (lit.) | [density ]
0.948 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.439(lit.) | [Fp ]
50°C | [storage temp. ]
Storage temp. 2-8°C | [solubility ]
Chloroform (Soluble), Ethyl Acetate (Slightly) | [form ]
clear liquid | [color ]
Colorless to Yellow | [InChI]
InChI=1S/C8H16O2/c1-9-8(10-2)6-4-3-5-7-8/h3-7H2,1-2H3 | [InChIKey]
XPIJMQVLTXAGME-UHFFFAOYSA-N | [SMILES]
C1(OC)(OC)CCCCC1 | [CAS DataBase Reference]
933-40-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Warning | [Hazard statements ]
H226 | [Precautionary statements ]
P210-P233-P240-P241-P242-P243 | [Risk Statements ]
R10:Flammable.
R18:In use may form flammable/explosive vapor-air mixture. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S51:Use only in well-ventilated areas . | [RIDADR ]
3271 | [WGK Germany ]
3 | [HS Code ]
2911.00.5000 | [HazardClass ]
3 | [PackingGroup ]
III | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 3 |
| Hazard Information | Back Directory | [Uses]
1,1-Dimethoxycyclohexane is a useful research chemical used in the preparation of N-??substituted valiolamine derivatives as potential oral antidiabetic agents. | [Synthesis Reference(s)]
Canadian Journal of Chemistry, 61, p. 366, 1983 DOI: 10.1139/v83-065
Tetrahedron Letters, 30, p. 6151, 1989 DOI: 10.1016/S0040-4039(01)93328-3 | [General Description]
Cyclohexanone dimethyl ketal reacts with trimethylsilane in the presence of trimethylsilyl triflate to form the corresponding ether. It can also undergo allylation and propargylation in the presence of indium to form the corresponding homoallylic or homopropargylic alcohol, respectively. |
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