| Identification | More | [Name]
BENZYL PHENYL ETHER | [CAS]
946-80-5 | [Synonyms]
BENZYLOXY-BENZENE
BENZYL PHENYL ETHER
PHENYL BENZYL ETHER
TIMTEC-BB SBB008247
(Phenoxymethyl)-benzene
alpha-Phenylanisole
Anisole, alpha-phenyl-
Ether, benzyl phenyl
Benzylphenylether,97%
Benzene, (phenoxymethyl)-
à-phenoxytoluene
Benzyl phenyl ether, Pract. | [Molecular Formula]
C13H12O | [MDL Number]
MFCD00020660 | [Molecular Weight]
184.23 | [MOL File]
946-80-5.mol |
| Chemical Properties | Back Directory | [Appearance]
Light brown-orange chunks | [Melting point ]
39-41 °C (lit.) | [Boiling point ]
286-287 °C (lit.) | [density ]
1.0120 (rough estimate) | [refractive index ]
1.5641 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Chunks | [color ]
Light brown-orange | [Water Solubility ]
Insoluble in water. | [BRN ]
2045713 | [InChI]
InChI=1S/C13H12O/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13/h1-10H,11H2 | [InChIKey]
BOTNYLSAWDQNEX-UHFFFAOYSA-N | [SMILES]
C1(COC2=CC=CC=C2)=CC=CC=C1 | [CAS DataBase Reference]
946-80-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29093090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Light brown-orange chunks | [Uses]
Benzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities. | [General Description]
Benzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals. It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities. |
| Questions And Answer | Back Directory | [Uses in Perfume]
Faint, sweet and remotely floral odor. However, most commercial products seem to have
a pronounced "Bitter Almond" note, probably deriving from impurities in this chemical.
Besides, benzyl phenyl ether does not seem to offer
any unusual or specifically desirable notes
which are not obtainable by means of other
and equally inexpensive perfume chemicals. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|