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97-06-3

97-06-3 Structure

97-06-3 Structure
IdentificationBack Directory
[Name]

2-NITROTOLUENE-4-SULFONIC ACID
[CAS]

97-06-3
[Synonyms]

2-NITROTOLUENE-4-SULFONIC ACID
O-NITROTOLUENE-P-SULFONIC ACID
2-nitro-p-toluenesulphonic acid
2-Nitro-4-Toluene Sulfonic Acid
4-METHYL-3-NITROBENZENSULFONIC ACID
4-methyl-3-nitro-benzenesulfonicaci
4-METHYL-3-NITROBENZENE SULFONIC ACID
4-methyl-3-nitrobenzene sulfonic aicd
ortho-nitro-toluene-para-sulphonicacid
1-METHYL-2-NITROBENZENE-4-SULFONIC ACID
Benzenesulfonic acid, 4-methyl-3-nitro-
1-Methyl-2-nitrobenzene-4-sulfonic acid o-Nitrotoluene-p-sulfonic acid
[EINECS(EC#)]

202-556-1
[Molecular Formula]

C7H7NO5S
[MDL Number]

MFCD00035917
[MOL File]

97-06-3.mol
[Molecular Weight]

217.2
Chemical PropertiesBack Directory
[Melting point ]

92°C
[Boiling point ]

500°C (rough estimate)
[density ]

1.6040 (rough estimate)
[refractive index ]

1.6100 (estimate)
[pka]

-1.04±0.50(Predicted)
[EPA Substance Registry System]

Benzenesulfonic acid, 4-methyl-3-nitro- (97-06-3)
Safety DataBack Directory
[TSCA ]

TSCA listed
Hazard InformationBack Directory
[Physical properties]

2-Nitrotoluene-4-sulfonic Acid, crystallizes from water as pale yellow hygroscopic needles of the dihydrate.
[Uses]

The total liquor of 2-Nitrotoluene-4-sulfonic Acid is hydrogenated in situ to give o-toluidine-4-sulfonic acid [618-03-1]. Isolated 2-nitrotoluene-4- sulfonic acid may be converted to 2-nitro-p-toluenesulfonyl chloride [54090-41-4], but the preferred process for [54090-41-4] is chlorosulfonation of 2-nitrotoluene. Reaction of [54090-41-4] with dimethylamine followed by reduction gives 3-amino-4-methyl-N,N-dimethylbenzenesulfonamide [6331-68-6] for use as an azoic diazo component.
[Production Methods]

2-Nitrotoluene is sulfonated by heating with 25 % oleum at 80 ℃ for 3 h, then quenching and liming to give a neutral solution of the sodium salt of 2-Nitrotoluene-4-sulfonic Acid.
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