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97-24-5

97-24-5 Structure

97-24-5 Structure
IdentificationMore
[Name]

BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE
[CAS]

97-24-5
[Synonyms]

2,2'-DIHYDROXY-5,5'-DICHLORODIPHENYL SULFIDE
2,2'-THIOBIS(4-CHLOROPHENOL)
BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE
BIS(5-CHLORO-2-HYDROXYPHENYL) SULFIDE
CHLORHYDROSULFIDE
CHLOROHYDROSULFIDE
FENTICHLOR
FENTICLOR
TIMTEC-BB SBB001172
2,2’-thiobis(4-chloro-pheno
2,2'-Dihydroxy-5,5'-dichlorophenyl sulfide
5,5'-Dichloro-2,2'-dihydroxydiphenyl sulfide
component of Banish
CR 305
cr305
D 25
D 25-Antimykotikum
d25
HL 1050
Meflorin
[EINECS(EC#)]

202-568-7
[Molecular Formula]

C12H8Cl2O2S
[MDL Number]

MFCD00031479
[Molecular Weight]

287.16
[MOL File]

97-24-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to pale yellow powder
[Melting point ]

175°C
[Boiling point ]

416.7±45.0 °C(Predicted)
[density ]

1.4186 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to crystal
[pka]

7.91±0.48(Predicted)
[color ]

White to Orange to Green
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Merck ]

4004
[Cosmetics Ingredients Functions]

ANTIMICROBIAL
[LogP]

4.400 (est)
[CAS DataBase Reference]

97-24-5(CAS DataBase Reference)
[EPA Substance Registry System]

Fenticlor (97-24-5)
Safety DataBack Directory
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RTECS ]

SN0350000
[HS Code ]

2930.90.2900
[HazardClass ]

IRRITANT
[Toxicity]

LDLo intraperitoneal in mouse: 250mg/kg
Hazard InformationBack Directory
[General Description]

White to cream-colored solid or pale yellow powder. White crystalline solid melting from 175.8-186.8°C. Odorless and insolbule in water.
[Reactivity Profile]

2,2'-THIOBIS(4-CHLOROPHENOL)(97-24-5) is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials may generate heat and toxic or flammable gases.
[Air & Water Reactions]

Insoluble in water.
[Hazard]

Toxic by ingestion.
[Fire Hazard]

Flash point data are not available for this chemical, but 2,2'-THIOBIS(4-CHLOROPHENOL) is probably combustible.
[Chemical Properties]

white to pale yellow powder
[Originator]

Fenticlor,Shanghai Lansheng
[Uses]

Fentichlor is a fungicide especially used against Monosporium apiospermum; topical antifungal and antibacterial agent in hairdressings, antifungal creams, and ointments; thermoplastic resin.
[Uses]

Fungicide; especially used against Monosporium apiospermum: Reifferscheid, Seeliger, Dtsch. Med. Wochenschr. 80, 1841, 1850 (1955).
[Definition]

ChEBI: An aryl sulfide having two 5-chloro-2-hydroxyphenyl groups attached to sulfur; an antiinfective drug mostly used in veterinary medicine.
[Preparation]

Fenticlor is produced (1) by the reaction of 4-chlorophenol with sulfur dichloride in the presence of AlCl3 or (2) by chlorination of 2,2'-thiobisphenol with chlorine in glacial acetic acid or with SO2Cl2 in dichlorobenzene. It shows a tendency to discoloration. Fenticlor has a broad range of antimicrobial action; it is, e.g., effective against bacteria, fungi, yeasts, and algae. Fenticlor is therefore used as a preservative for aqueous functional fluids and to control algae and slime in process water circulation systems.
[Manufacturing Process]

1 mol bis(2-hydroxy-phenyl)-sulfide, prepared from sulfuryl chloride and phenol, in about 2500 ml glacial acetic acid was dissolved and heated for boiling. 2-3 mol gaseous chlorine was passed through that solution and on cooling bis(2-oxy-5-chlorphenyl)sulfide was fallen. It was recrystallized from acetic acid or light petroleum. MP: 175°C. A residue was dropped from filtrate with water as the white crystals, which melted at the same temperature.
Fenticlor may be also prepared by adding sulfuryl chloride to the solution of bis(2-hydroxy-phenyl)sulfide in dichlorobenzene
[Therapeutic Function]

Antifungal
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE(97-24-5)MS
BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE(97-24-5)1HNMR
BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE(97-24-5)13CNMR
BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE(97-24-5)IR1
BIS(2-HYDROXY-5-CHLOROPHENYL) SULFIDE(97-24-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

97-24-5(sigmaaldrich)
[TCI AMERICA]

Bis(2-hydroxy-5-chlorophenyl) Sulfide,>98.0%(GC)(T)(97-24-5)
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