ChemicalBook--->CAS DataBase List--->99326-34-8

99326-34-8

99326-34-8 Structure

99326-34-8 Structure
IdentificationBack Directory
[Name]

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
[CAS]

99326-34-8
[Synonyms]

Bis(1,5-cyclooctadie
Bis(1,5-cyclooctadiene)
Bis(1,5-cyclooctadiene)rhodium triflate
BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TRIFL&
Bis(1,5-cyclooctadiene)rhodium(I) triflate
BIS(1,5-CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
BIS(1,5-CYCLOOCTADIENE)-TRIFLUOROMETHANESULFITORHODIUM (I)
Bis-(1,5-cyclooctadiene)-rhodium trifluoromethanesulfonate
Bis(1,5-cyclooctadiene)rhodium(Ⅰ) trifluoromethanesulfonate
Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulphonate99%
Bis(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate,99%
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate,97%
Bis(1,5-cyclooctadiene)rhodiuM(I) trifluoroMethanesulfonate 98%
1,5-Cyclooctadiene(hydroquinone)rhodiuM(I) tetrafluoroborate,98%
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 99%
Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethane sulphonate 98+%
[Molecular Formula]

C17H24F3O3RhS
[MDL Number]

MFCD00143752
[MOL File]

99326-34-8.mol
[Molecular Weight]

468.34
Chemical PropertiesBack Directory
[Appearance]

dark red crystals
[Melting point ]

159 °C (dec.)(lit.)
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

Soluble in chloroform
[form ]

crystal
[color ]

dark red
[Water Solubility ]

insoluble
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
[InChI]

1S/2C8H12.CHF3O3S.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h2*1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b2*2-1-,8-7-;;
[InChIKey]

GOPBTCMAUMSOBX-QMDOQEJBSA-M
[SMILES]

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
Hazard InformationBack Directory
[Chemical Properties]

dark red crystals
[Uses]

[reaction suitability]

core: rhodium
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Hazard Note ]

Irritant
[TSCA ]

No
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Questions And AnswerBack Directory
[Reaction]

  1. Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3-diynes to ethyl glyoxalate
  2. Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen
  3. Rhodium catalyzed asymmetric synthesis of Sitagliptin
  4. Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones
Reactions of 99326-34-8_1
Reactions of 99326-34-8_2
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