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35138-22-8

35138-22-8 Structure

35138-22-8 Structure
IdentificationMore
[Name]

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
[CAS]

35138-22-8
[Synonyms]

BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE
BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE
BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE
RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX
BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&
Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%
Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
[Molecular Formula]

C16H24BF4Rh
[MDL Number]

MFCD00075045
[Molecular Weight]

406.07
[MOL File]

35138-22-8.mol
Chemical PropertiesBack Directory
[Appearance]

dark red
[mp ]

210 °C
[storage temp. ]

Refrigerator (+4°C)
[Water Solubility ]

insoluble
[Sensitive ]

Slightly air & moisture sensitive
[CAS DataBase Reference]

35138-22-8(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Moisture sensitive;Heat sensitive;Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R34:Causes burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 2921
[Hazard Note ]

Irritant
[HS Code ]

28439000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Etanol-->Ethyl acetate-->1,5-Cyclooctadiene-->Silver tetrafluoroborate -->Rhodium (III) chloride trihydrate
Questions And AnswerBack Directory
[Uses]

  1. Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
  2. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions. 
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(35138-22-8)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(35138-22-8)
[Alfa Aesar]

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate(35138-22-8)
[Sigma Aldrich]

35138-22-8(sigmaaldrich)
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