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506-77-4

中文名称 氯化氰
英文名称 Cyanogen chloride
CAS 506-77-4
分子式 CClN
分子量 61.47
MOL 文件 506-77-4.mol
506-77-4 结构式 506-77-4 结构式

基本信息

中文别名
氯化氰
氯甲腈
氰化氯
英文别名
Chlorine cyanide
Chlorocyan
chlorocyanogen
Cyanogen chloride
Cyanogen chloride ((CN)Cl)
Chlorcyan
Chloro cyanide
Cyan chloride
RCRA waste number P-033
所属类别
有机原料:腈类化合物

物理化学性质

外观性质无色液体或气体,有催泪性。
溶解性溶于水、乙醇、乙醚等。
熔点-6°
沸点14°C
密度1.186
蒸气压60kPa at 0℃
溶解度soluble in H2O, ethanol, ethyl ether
形态无色气体
颜色colorless vol liquid or gas
水溶解性soluble H2O, ether, alcohol [MER06]
比热容Cp(gas):0.732064J/(g·K),at 25℃
Henry's Law Constant1.2×10-2 mol/(m3Pa) at 25℃, Hilal et al. (2008)
暴露限值Ceiling limit 0.7 mg/m3 (0.3 ppm) (ACGIH).
LogP0.64 at 20℃
CAS 数据库506-77-4
NIST化学物质信息Cyanogen chloride(506-77-4)

安全数据

危险性符号(GHS)环境危害 (GHS09)腐蚀 (GHS05)压缩气体 (GHS04)有毒 (GHS06)
GHS09,GHS05,GHS04,GHS06
警示词危险
危险品标志T
危险品运输编号UN 1589
职业暴露限值Ceiling: 0.3 ppm (0.6 mg/m3)
TSCATSCA listed
REACH 注册登记Active
危险等级2.3
毒性CK may polymerize violently if contaminated with hydrogen chloride or ammonium chloride. Upon heating, it decomposes, producing toxic and corrosive fumes of hydrogen cyanide, hydrochloric acid, and nitrogen oxides. Hazardous polymerization can occur. Cyanogen chloride will react slowly with water to form hydrogen chloride gas. It acts on the body in two ways. Systemic effects of CK are much like those of hydrogen cyanide. Additionally, it causes irritation of the eyes, upper respiratory tract, and lungs. Eye irritation results in tearing. CK, like AC, stimulates the respiratory system and rapidly paralyzes it. Exposure is followed by immediate, intense irritation of the nose, throat, and eyes, with coughing, tightness in the chest, and lacrimation. This is followed by dizziness and increasing difficulty breathing. Unconsciousness comes next, with failing respiration and death within a few minutes. Convulsions, retching, and involuntary urination and defecation may occur. If these effects are not fatal, the signs and symptoms of pulmonary edema may develop. There may be repeated coughing, with profuse foamy sputum, rales in the chest, severe dyspnea, and distinct cyanosis. Recovery from the systemic effects is usually as prompt as in AC poisoning. However, a higher incidence of residual damage to the central nervous system should be expected. Based upon the concentration of the cyanogen chloride to which the victim has been exposed, the pulmonary effects may evolve instantly or may be delayed until the systemic effects have subsided. Consequently, early prognosis must be cautious.

常见问题列表

应用
用于制备双酚A氰酸酯
用途
可用作有机合成和医药中间体,用于制备氯磺酰异氰酸酯。
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