2-Methacryloyloxy-2-methyladamantane

2-Methacryloyloxy-2-methyladamantane Struktur
177080-67-0
CAS-Nr.
177080-67-0
Englisch Name:
2-Methacryloyloxy-2-methyladamantane
Synonyma:
2-METHYL-2-ADAMANTYL METHACRYL;-Methyl-2-adamantylmethacrylate;2-Ethy1-2-adamantylmethacrylate;2-Methyl-2-adaMantyl Methacrylte;2-Methyl-2-adamantyl methacrylate;2-MethyladaMantan-2-yl Methacrylate;2-methacryloyloxy-2-methyladamantane;2-Methyl-2-adamantyl methacrylate (MADMA);Methacrylic Acid 2-Methyl-2-adamantyl Ester;2-Methyl-2-adamantylmethacrylate 177080-67-0
CBNumber:
CB31483683
Summenformel:
C15H22O2
Molgewicht:
234.33
MOL-Datei:
177080-67-0.mol

2-Methacryloyloxy-2-methyladamantane Eigenschaften

Siedepunkt:
301.3±11.0 °C(Predicted)
Dichte
1.06±0.1 g/cm3(Predicted)
Brechungsindex
1.5050 to 1.5090
Flammpunkt:
120°C(lit.)
storage temp. 
2-8°C
Aggregatzustand
clear liquid
Farbe
Colorless to Almost colorless
Wichte
1.06
Sensitive 
Heat Sensitive
InChI
InChI=1S/C15H22O2/c1-9(2)14(16)17-15(3)12-5-10-4-11(7-12)8-13(15)6-10/h10-13H,1,4-8H2,2-3H3
InChIKey
FDYDISGSYGFRJM-UHFFFAOYSA-N
SMILES
C(OC1(C)C2CC3CC1CC(C3)C2)(=O)C(C)=C
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
HS Code  2902190000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

2-Methacryloyloxy-2-methyladamantane Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Off-white powder.

Application

2-Methacryloyloxy-2-methyladamantane as a guest molecule can be introduced onto the silicon substrate by interacting with β-cyclodextrin (β-CD) to construct supramolecular composite surfaces. After the assembly of hydrophilic guest molecules on the main surface, the wettability, water lubrication and resistance to algal cell adhesion of the supramolecular composite surface were improved. This host-guest interface supramolecule provides a new way to prepare water-based lubrication and antifouling materials[2].

Synthese

The synthesis of 2-Methyl-2-adamantylmethacrylate is as follows:Add 3546ml of n-heptane in the 5L four-necked flask equipped with stirring paddle, condenser tube and thermometer, turn on stirring, add 126.3g of 2-methyladamantanol to the system, and slowly add 0.022g polymerization inhibitor tetrachlorobenzoquinone to the reaction, add 110.8g basic ion exchange resin, adjust pH=7-8, cool down to -13°C, slowly add 110.8g vinyl methacrylate dropwise to the reaction system, keep the reaction for 7h, monitor the reaction progress, and take samples for detection After the reaction was completed, 1000 ml of water was added to the reaction system, and the mixture was stirred and extracted for phase separation. The organic phase was dried, concentrated under reduced pressure and evaporated to dryness to obtain 167 g of 2-methyl-2-adamantyl methacrylate (2-Methacryloyloxy-2-methyladamantane) product with a yield of 93.78%.

177080-67-0.png

Einzelnachweise

[1] M. Maríc. “Nitroxide‐mediated polymerization of adamantyl‐functional methacrylates for 193 nm photoresists.” Canadian Journal of Chemical Engineering 95 1 (2017): 708–716.
[2] RONGNIAN XU. Promoting Lubricity and Antifouling Properties by Supramolecular-Recognition-Based Surface Grafting[J]. Langmuir, 2018. DOI:10.1021/acs.langmuir.8b02375.

2-Methacryloyloxy-2-methyladamantane Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2-Methacryloyloxy-2-methyladamantane Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 150)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Changzhou waston chemical technology Co.,Ltd
+86-051985861892 +8618112881323
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Shanghai Z&T Chemical Co., Ltd
+86-021-33561011 +8613818804961
Sales@ztchemical.com.cn China 402 58
Heynova (Shanghai) New Material Technology CO., Ltd
+86-17821320848; +8617821320848
zoe@heynovachem.com China 173 58
Shanghai Joiny Pharmaceutical Co.,LTD
+8613681955282
gyd@joiny-pharma.com China 250 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 18632 58
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29888 58
Shanghai Arbor Chemical Co., Ltd.
021-60451682
act@arborchemical.com CHINA 906 58
Biochempartner
0086-13720134139
candy@biochempartner.com CHINA 967 58
QINGDAO HONG JIN CHEMCIAL CO.,LTD.
532-83657313
hjt@hong-jin.com China 228 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715
admin@nexconn.com China 10311 58

177080-67-0()Verwandte Suche:


  • 2-methacryloyloxy-2-methyladamantane
  • 2-Methacryloyloxy-2-MethyladaMantane (stabilized with MEHQ)
  • 2-Methyl-2-adamantyl Methacrylate Methacrylic Acid 2-Methyl-2-adamantyl Ester
  • 2-Methyl-2-adaMantyl Methacrylte
  • 2-Methyl-2-adamantyl methacrylate
  • 2-METHYL-2-ADAMANTYL METHACRYL
  • 2-MethyladaMantan-2-yl Methacrylate
  • 2-Methyl-2-Adamantyl Methacrylate MAMA ArF monomers
  • 2-Methyl-2-adamantylmethacrylate 177080-67-0
  • 2-Methacryloyloxy-2-methyladamantane 177080-67-0
  • 2-Methacryloyloxy-2-methyladamantane(stabilizedwithMEHQ)>
  • 2-Propenoic acid, 2-methyl-, 2-methyltricyclo[3.3.1.13,7]dec-2-yl ester
  • Methacrylic Acid 2-Methyl-2-adamantyl Ester
  • (2-methyl-2-adamantyl) 2-methylprop-2-enoate
  • 2-Methyl-2-adamantyl methacrylate (MADMA)
  • -Methyl-2-adamantylmethacrylate
  • (1r,5R,7S)-2-methyladamantan-2-yl methacrylate
  • 2-Ethy1-2-adamantylmethacrylate
  • 177080-67-0
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