Azinphos-ethyl (ISO)

AZINPHOS-ETHYL Struktur
2642-71-9
CAS-Nr.
2642-71-9
Bezeichnung:
Azinphos-ethyl (ISO)
Englisch Name:
AZINPHOS-ETHYL
Synonyma:
Gutex;R 1513;Azinos;Bionex;B-16259;sepizinl;bay16255;bay16259;Sepizin L;BAY 16255
CBNumber:
CB3368633
Summenformel:
C12H16N3O3PS2
Molgewicht:
345.38
MOL-Datei:
2642-71-9.mol

Azinphos-ethyl (ISO) Eigenschaften

Schmelzpunkt:
45-47℃
Siedepunkt:
111°C
Dichte
1.43
Dampfdruck
3.2 x 10-4 Pa (20 °C)
storage temp. 
0-6°C
Wasserlöslichkeit
4.5 mg l-1(20 °C)
pka
-2.59±0.20(Predicted)
Aggregatzustand
Solid
BRN 
297468
CAS Datenbank
2642-71-9(CAS DataBase Reference)
EPA chemische Informationen
Azinphos-ethyl (2642-71-9)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher T+,N
R-Sätze: 24-28-50/53
S-Sätze: 28-36/37-45-60-61
RIDADR  2783
WGK Germany  3
RTECS-Nr. TD8400000
HazardClass  6.1(a)
PackingGroup  II
Giftige Stoffe Daten 2642-71-9(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H300 Lebensgefahr bei Verschlucken. Akute Toxizität oral Kategorie 2 Achtung GHS hazard pictogramssrc="/GHS06.jpg" width="20" height="20" /> P264, P270, P301+P310, P321, P330,P405, P501
H311 Giftig bei Hautkontakt. Akute Toxizität dermal Kategorie 3 Achtung GHS hazard pictogramssrc="/GHS06.jpg" width="20" height="20" /> P280, P302+P352, P312, P322, P361,P363, P405, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

Azinphos-ethyl (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R24:Giftig bei Berührung mit der Haut.
R28:Sehr giftig beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

S-Sätze Betriebsanweisung:

S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Chemische Eigenschaften

Azinphos-ethyl forms colorless, clear crystals. It is insoluble in water, but soluble in most organic solvents. As an acaricide, azinphos-ethyl is used for the control of pests, such as, spider mites, aphids, caterpillars, potato bug, beetles, bollweevils, whitefl ies, bollworms, thrips, and other biting and sucking insects. Human exposures to azinphos-ethyl occur through absorption from the gastrointestinal tract, through the intact skin, and by inhalation of fi ne spray mist and dusts.
Azinphos-ethyl is a non-systemic organophosphorus insecticide, which is used against a relatively broad spectrum of insects. These include lepidopterous larvae, beetles and their larvae, aphids, jassids, and spider mites on various crops. And also crops of cotton, rice, sugar and fodder beets, fruits such as apples, pears, citrus-fruit, grapes; tobacco. Many countries around the world have stopped the use of this pesticide.

Verwenden

Azinphos-ethyl is used to control both chewing and sucking pests on a wide range of crops.

Allgemeine Beschreibung

Colorless crystals. Used as a non-systemic insecticide with good ovicidal properties and long persistence. Used on cotton, citrus, vegetables, potatoes, tobacco, rice, and cereals to control caterpillars, beetles, aphids, spiders and many other insects. Not registered for use in the U.S.

Air & Water Reaktionen

Nearly insoluble in water. What little amount is solubilized will readily hydrolyze.

Reaktivität anzeigen

The BPS Pesticide incident in Helena resulted in an explosion and death of three firemen. The burning of a 1,000 pound sack of Azinphos Methyl or the flashing of Maneb which was present on the facility may have caused the explosion. Azinphos Ethyl may behave similarly. At elevated temperatures, AZINPHOS-ETHYL will decompose generating toxic gases.

Health Hazard

The systemic effects of AZINPHOS-ETHYL are similar to parathion. It is an extremely potent systemic toxicant via ingestion, inhalation and skin contact. It may cause death or permanent injury after very short exposure to small quantities.

Brandgefahr

(Non-Specific -- Organophosphorus Pesticide, n.o.s.) When heated to decomposition, AZINPHOS-ETHYL emits very toxic fumes of sulfur, phosphorus and nitrogen oxides. Container may explode in heat of fire.

Sicherheitsprofil

Poison by ingestion, inhalation, skin contact, and intraperitoneal route. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits toxic fumes of SOx, POx,, and NOx. See also PARATHION.

Stoffwechselwegen

Although the metabolism of azinphos-ethyl has been studied much less than that of azinphos-methyl, the biotransformations which have been reported appear to be totally analogous.

Vorsichtsmaßnahmen

Azinphos-ethyl is an organophosphorus compound that inhibits cholinesterase enzymes. It is very toxic and occupational workers should be very careful during use, storage, and waste disposal of it.

Azinphos-ethyl (ISO) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

2642-71-9(Azinphos-ethyl (ISO))Verwandte Suche:


  • S-(3,4-DIHYDRO-4-OXOBENZO[D]-[1,2,3]-TRIAZINE-3-YLMETHYL)O,O-DIETHYL PHOSPHORODITHIOATE
  • R 1513
  • O,O-DIETHYL-S-[4-OXO-1,2,3-BENZO TRIAZIN-3-[4H]-YLMETHYL]PHOSPHORODITHIOATE
  • ,3-benzotriazin-4(3h)-one
  • 3,4-Dihydro-4-oxo-3-benzotriazinylmethyl O,O-diethyl phosphorodithioate
  • Azinos
  • AZINPHOS-ETHYL
  • AZINUGEC E
  • BAYER 16259
  • GUSATHION A(R)
  • Phosphordithioicacid,O,O-diethyl-S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl]ester
  • Phosphorodithioic acid, O,O-diethyl ester, S-ester with 3-(mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one
  • Phosphorodithioic acid, O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] ester
  • phosphorodithioicacid,o,o-diethylester,s-esterwith3-(mercaptomethyl)-1,2
  • phosphorodithioicacid,o,o-diethylester,s-esterwith3-(mercaptomethyl)-1,2,
  • phosphorodithioicacid,o,o-diethyls-((4-oxo-1,2,3-benzotriazin-3(4h)-yl)methy
  • phosphorodithioicacid,O,O-diethylS-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl]ester
  • S-(3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl) O,O-diethyl phosphorodithioate
  • s-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl)o,o-diethylphosphorodith
  • s-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl)o,o-diethylphosphorodithio
  • S-(3,4-Dihydro-4-oxobenzo [d]-[1,2,3]-triazin-3-ylmethyl) OO-diethyl phosphorodithioate
  • s-3,4-dihydro-4-oxobenzo(d)(1,2,3)triazin-3-ylmethyl)o,o-diethylphosphorodithi
  • Sepizin L
  • sepizinl
  • Triazotion
  • triazotion(russian)
  • 3,4-dihydro-4-oxo-3-benzotriazinylmethylo,o-diethylphosphorodithioate
  • 3-benzotriazin-4(3h)-one
  • 3-diethyloxyphosphinothioylthiomethyl-1,2,3-benzotriazin-4(3h)-one
  • Athyl-gusathion
  • azin-4(3h)-one
  • Azinfos-ethyl
  • Azinophos-ethyl
  • Azinphos-aethyl
  • Azinphos-etile
  • BAY 16255
  • Bay 16259
  • bay16255
  • bay16259
  • Gusathion ethyl
  • Gusathion H
  • Gusathion H and K
  • Gusathion K forte
  • gusathiona
  • gusathiona-m
  • gusathionh
  • gusathionhandk
  • gusathionkforte
  • Gusation A
  • gusationa
  • Gutex
  • in-4(3h)-one
  • O,O-Diaethyl-S-((4-oxo-3H-1,2,3-benzotriazin-3-yl)-methyl)-dithiophosphat
  • o,o-diaethyl-s-((4-oxo-3h-1,2,3-benzotriazin-3-yl)-methyl)-dithiophosphat(germ
  • O,O-Diaethyl-S-(4-oxobenzotriazin-3-methyl)-dithiophosphat
  • O,O-Diethyl phosphorodithioate S-ester with 3-(mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one
  • O,O-Diethyl S-(4-oxobenzotriazino-3-methyl)phosphorodithioate
  • O,O-Diethyl S(4-oxobenzyltriazine-3-methyl) dithiophosphate
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