Trifluoromethyl iodide
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- CAS-Nr.
- 2314-97-8
- Englisch Name:
- Trifluoromethyl iodide
- Synonyma:
- CF3I;Trifluoroiodomethane;CIF3;IODOTRIFLUOROMETHANE;R13I1;FIC-1311;FIC-13I1;freon13t1;Freon13I1;uoroiodomethane
- CBNumber:
- CB7356124
- Summenformel:
- CF3I
- Molgewicht:
- 195.91
- MOL-Datei:
- 2314-97-8.mol
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Trifluoromethyl iodide Eigenschaften
- Schmelzpunkt:
- <−78 °C(lit.)
- Siedepunkt:
- −22.5 °C(lit.)
- Dichte
- 2.361
- Dampfdruck
- 540.5kPa at 25℃
- Brechungsindex
- 1.379
- Flammpunkt:
- -22.5°C
- Aggregatzustand
- Gas
- Wasserlöslichkeit
- Slightly soluble in water.
- Sensitive
- Light Sensitive
- BRN
- 1732740
- Stabilität:
- Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable.
- LogP
- 2.41 at 22.85℃
- CAS Datenbank
- 2314-97-8(CAS DataBase Reference)
- NIST chemische Informationen
- Methane, trifluoroiodo-(2314-97-8)
- EPA chemische Informationen
- Trifluoroiodomethane (2314-97-8)
Trifluoromethyl iodide Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R68:Irreversibler Schaden möglich.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
Chemische Eigenschaften
colourless gas
Verwenden
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
synthetische
A glass flask provided with a gas outlet is filled with 80 g. (0.153 mole) of CI4 and 30 g. (0.135 mole) of IF5. The gas outlet is connected via short rubber tubes to several gas traps cooled with liquid nitrogen. Agitation of the vessel produces vigorous evolution of gas. When the reaction subsides, the system is heated for 30 min at 90-100°C. The condensate in the gas traps is then washed with 5% NaOH and fractionated. The yield is 90%.
Synthesis Reference(s)
Journal of the American Chemical Society, 107, p. 5014, 1985
DOI: 10.1021/ja00303a042
Trifluoromethyl iodide Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Trifluoromethyl iodide Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 191)Lieferanten
2314-97-8()Verwandte Suche:
- PERFLUOROMETHYL IODIDE
- Freon13I1
- freon13t1
- iodotrifluoromethane(trifluoromethyliodide)
- Methane,trifluoroiodo-
- monoiodotrifluoromethane
- Trifluoromethyl iodide 99%
- R13I1
- Trifluoriodmethan
- Trifluoriodomethane
- trifluoroiodo-methan
- TRIFLUOROMETHYL IODIDE
- TRIFLUOROMETHYL IODIDE CYLINDER WITH
- Trifluoromethyliodide,min.97%
- Iodotrifluoromethane 99%
- Iodotrifluoromethane99%
- Trifluoroiodomethane,Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide
- Trifluoromethyliodide, min. 97% (Material sold in non-returnable cylinder)
- Trifluoroiodomethane, 99.9%
- Trifluoroiodomethane, 97+%
- trifluoroiodomethane trifluoromethyl iodide
- Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide
- Trifluoromethyliodide, min. 97%
- 7-Trifluoromethyl-1H-indole-2-carboxylicacidethylester
- Trifluoromethyl iodide 85% 99.5%
- uoroiodomethane
- Trifluoromethane iodide
- FIC-1311
- FIC-13I1
- CF3I
- CIF3
- IODOTRIFLUOROMETHANE
- Trifluoroiodomethane
- Trifluoroiodomethane CF3I
- Trifluorolodmethane
- 2314-97-8
- Synthetic Reagents
- Compressed and Liquefied Gases
- organofluorine compounds
