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[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en

(-)-ISOCARYOPHYLLENE Struktur
118-65-0
CAS-Nr.
118-65-0
Bezeichnung:
[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en
Englisch Name:
(-)-ISOCARYOPHYLLENE
Synonyma:
BETA-CARYOPHYLLENE;Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-,[1R-(1R*,4Z,9S*)]-;(Z)-beta-caryophyllene;Bicyclo7.2.0undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1R,4Z,9S)-;(1R,4Z,9S)-4,11,11-trimethyl-8-methylidenebicyclo[7.2.0]undec-4-ene;4,11,11-trimethyl-8-methylene-,[1R-(1R*,4Z,9S*)]-Bicyclo[7.2.0]undec-4-ene;,9s)]-;(-)-ISOCARYOPHYLLENE;(-)-ISOCARYOPHYLLENE;ISOCARYOPHYLLENE, (-)-
CBNumber:
CB7730612
Summenformel:
C15H24
Molgewicht:
204.35
MOL-Datei:
118-65-0.mol
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[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en Eigenschaften

Schmelzpunkt:
25°C
alpha 
D -24° (chloroform)
Siedepunkt:
271-273 °C(lit.)
Dichte
0.893 g/mL at 20 °C(lit.)
Brechungsindex
n20/D 1.496
Flammpunkt:
215 °F
storage temp. 
2-8°C
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Oil
Farbe
Colourless
Geruch (Odor)
at 100.00 %. woody spicy
Geruchsart
woody
Stabilität:
Light Sensitive
LogP
6.416 (est)
EPA chemische Informationen
Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1R,4Z,9S)- (118-65-0)

Sicherheit

S-Sätze: 23-24/25
WGK Germany  3
F  10-23

[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en Chemische Eigenschaften,Einsatz,Produktion Methoden

S-Sätze Betriebsanweisung:

S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.

Verwenden

In perfumery.

läuterung methode

Purify it by vacuum distillation or GLC using a nitrile-silicone column [Corey et al. J Am Chem Soc 86 485 1964, Ramage & Simonsen J Chem Soc 741 1936, Kumar et al.Synthesis 461 1976]. [Beilstein 5 III 1085.]

[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

[1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 22)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hubei Jusheng Technology Co.,Ltd. 		18871490254
linda@hubeijusheng.com CHINA 28180 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490
 info@gihichemicals.com China 49999 58
China National Standard Pharmaceutical Corporation Limited 		+8615391658522
 overseasales@yongstandards.com China 11927 58
Shanghai wencai New Material Technology Co., Ltd. 15721586846
 wencaimat@163.com China 2796 58
Shaanxi Dideu Medichem Co. Ltd 029-81124267 15229202216
 1073@dideu.com China 10011 58
Shanghai Maclean Biochemical Technology Co., LTD 021-50706066 15221275939
 shenlinxing@macklin.cn China 29803 58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 025-66113011 18112977050
 cb5@aikonchem.com China 10529 58

118-65-0([1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en)Verwandte Suche:

[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan 4,4,8-Trimethyltricyclo[6.3.1.02,5]dodecan-1-ol Caryophyllen [1R-(1R*,4Z,9S*)]-4,11,11-Trimethyl-8-methylenbicyclo[7.2.0]undec-4-en
  • ,9s)]-
  • bicyclo[7.2.0]undec-4-ene,4,11,11-trimethyl-8-methylene-,[1theta-(1theta,4z
  • (-)-ISOCARYOPHYLLENE
  • ISOCARYOPHYLLENE, (-)-
  • (1R,9S)-8-METHYLEN-4,11,11-TRIMETHYL-BICYCLO[7.2.0]UNDEC-4-ENE
  • (1R,9S,4Z)-4,11,11-Trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene
  • [1R,4Z,9S,(-)]-4,11,11-Trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene
  • (1r-(1r*,4z,9s*))-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undec-4-ene
  • (1r-(1r,4z,9s))-4,11,11-trimethyl
  • (1r-(1r,4z,9s))-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undec-4-ene
  • 4,11,11-trimethyl-8-methylene-, [1R-(1R*,4Z,9S*)]-Bicyclo[7.2.0]undec-4-ene bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-, [1 theta-(1 theta,4z ,9s)]- (-)-isocaryophyllene
  • (-)-ISOCARYOPHYLLENE
  • Bicyclo[7.2.0]undec-4-ene, 4,11,11-trimethyl-8-methylene-,[1R-(1R*,4Z,9S*)]-
  • (Z)-beta-caryophyllene
  • (1R,4Z,9S)-4,11,11-trimethyl-8-methylidenebicyclo[7.2.0]undec-4-ene
  • 4,11,11-trimethyl-8-methylene-,[1R-(1R*,4Z,9S*)]-Bicyclo[7.2.0]undec-4-ene
  • BETA-CARYOPHYLLENE
  • Bicyclo7.2.0undec-4-ene, 4,11,11-trimethyl-8-methylene-, (1R,4Z,9S)-
  • Eugenol Impurity 28 (Isocaryophyllene)
  • Picosulfate Disodium Said
  • 118-65-0
  • Asymmetric Synthesis
  • Organic Building Blocks
  • Alkenes
  • Chiral Building Blocks
  • pharmacetical
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