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[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan

CARYOPHYLLENE OXIDE Struktur
1139-30-6
CAS-Nr.
1139-30-6
Bezeichnung:
[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan
Englisch Name:
CARYOPHYLLENE OXIDE
Synonyma:
(-)-CARYOPHYLLENE OXIDE;(-)-EPOXYCARYOPHYLLENE;Caryophylene oxide;Caryophyllene epoxide;Caryophyllene oxyde;(-)-beta-Caryophyllene epoxide;caryophyleneoxide;CARYOPHYLLENEPOXID;5-oxatricyclo(8.20.0(4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r,4r,6r,1;0s)-
CBNumber:
CB3199893
Summenformel:
C15H24O
Molgewicht:
220.35
MOL-Datei:
1139-30-6.mol
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[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan Eigenschaften

Schmelzpunkt:
62-63 °C(lit.)
Siedepunkt:
301.3°C (rough estimate)
Dichte
0.96
Brechungsindex
1.4956
FEMA 
4085 | BETA-CARYOPHYLLENE OXIDE
Flammpunkt:
>230 °F
storage temp. 
2-8°C
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Crystalline Powder
Farbe
White
Geruch (Odor)
at 100.00 %. sweet fresh dry woody spicy
Geruchsart
woody
Optische Aktivität
[α]20/D 71±1°, c = 2% in chloroform
Wasserlöslichkeit
insoluble in water
JECFA Number
1575
BRN 
148213
LogP
4.57
EPA chemische Informationen
5-Oxatricyclo[8.2.0.04,6]dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)- (1139-30-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/38
S-Sätze: 26
WGK Germany  2
RTECS-Nr. RP5530000
F  1-10
HS Code  29109000
Giftige Stoffe Daten 1139-30-6(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 2
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/38:Reizt die Augen und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Caryophyllene oxide which has a woody, slightly ambergris-like odor, can be prepared by treatment of ??-caryophyllene with organic peracids.

Occurrence

Reported found in Nepeta betonicifolia C.A. Meyer oil Turkey (39.20%), geranium rose-scented oil (Pelargonium spp.) Cuba (14.70%), melissa oil (9.99%), guava leaf oil Cuba (8.20%), etc.

Verwenden

β-Caryophyllene Epoxide, and its derivatives has shown to have microbial transformation and butyrylcholinesterase inhibitory activity. It is also the main active constituent of essential oils obtained from various plants, used for flavoring and fragrances.

Definition

ChEBI: A natural product found in Cupania cinerea.

Sicherheitsprofil

Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

läuterung methode

Purify the oxide by TLC on silica gel with EtOAc/pet ether (b 60-80o) (15:85), and recrystallise it from MeOH or *C6H6. [NMR: Warnhoff Can J Chem 42 1664 1964, Ramage & Whitehead J Chem Soc 4336 1954, Beilstein 17 IV 392.]

[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

[1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 155)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578
 sales@hbmojin.com China 12456 58
Ouhuang Engineering Materials (Hubei) Co., Ltd 		+8617702722807
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Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512
 info@tianfuchem.com China 21691 55
Shanghai Zheyan Biotech Co., Ltd. 		18017610038
zheyansh@163.com CHINA 3620 58
career henan chemical co 		+86-0371-86658258
sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254
linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd. 		+86-19930503282
 alice@crovellbio.com China 8823 58
Shaanxi Pioneer Biotech Co., Ltd . 		+8613259417953
 sales@pioneerbiotech.com China 3000 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873
 sales@chemdad.com China 39916 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-87569266 15319487004
 1015@dideu.com China 2263 58

1139-30-6([1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan)Verwandte Suche:

(R*,R*)-α,4-Dimethyl-α-(4-methyl-3-pentenyl)cyclohex-3-en-1-methanol Zitronensure Ethanol Glycerol Salicylsäure Caryophyllen Humulen Methyl-(3β)-3-hydroxyolean-12-en-28-oat [1R-(1R*,4R*,6R*,10S*)]-4,12,12-Trimethyl-9-methylen-5-oxatricyclo[8.2.0.04,6]dodecan 2-Methyl-6-methylenoct-7-en-2-ol, Dihydroderivat 5,6-Epoxyhex-1-en
  • (-)-5-Oxatricyclo[8.2.0.0(4,6)]dodecane,4,12,12-trimethyl-9-methylene-, [1R-(1R*,4R*,6R*,10S*)]-
  • caryophylleneepoxide
  • (1R,4R,6R,10S)-9-METHYLENE-4,12,12-TRIMETHYL-5-OXATRICYCLO[8.2.0.0(4,6)]DODECANE
  • CARYOPHYLLENE OXIDE
  • caryophylleneoxide,(1R,4R,6R,10S)-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.0]4,6)]dodecane
  • 5-Oxatricyclo8.2.0.04,6dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)-
  • (1R-(1R*,4R*,6R*,10S*))-4,12,12-Trimethyl-9-methylen-5-oxatricyclo(8.2.0.04,6)dodecan
  • (-)-Epoxycaryophyllene, (1R,4R,6R,10S)-9-Methylene-4,12,12-trimethyl-5-oxatricyclo[8.2.0.04,6]dodecane
  • (1R,4R,6R,10S)-4,12,12-Trimethyl-9-methylene-5-oxatricyclo[8.2.0.04,6]dodecane
  • (1R,5S,8R,11R)-4-Methylene-7,7,11-trimethyl-12-oxatricyclo[9.1.0.05,8]dodecane
  • (1β,4R,5R,9α)-4,11,11-Trimethyl-8-methylene-4,5-epoxybicyclo[7.2.0]undecane
  • (-)-Caryophyllene oxide,97%
  • (-)-CARYOPHYLLENE OXIDE 95%
  • CARYOPHYLLENE OXIDE TECH. 90%
  • CARYOPHYLLENE OXIDE 95+%
  • (-)-beta-caryophylleneepoxid
  • (-)-beta-caryophylleneepoxide
  • (-)-Epoxydihydrocaryophyllene
  • (1r-(1r*,4r*,6r*,10s*))-4,12,12-trimethyl-9-methylene-5-oxatricyclo(8.2.0.04,6)dodecane
  • (1r-(1r,4r,6r,10s))-4,12,12-trimethyl
  • (1r-(1r,4r,6r,10s))-4,12,12-trimethyl-9-methylene-5-oxatricyclo(8.2.0.04,6)dodecane
  • ,6r,10s)-
  • 0s)-
  • 4,11,11-Trimethyl-8-methylene-5-oxatricyclo(8.2.0.0(4,6))dodecane
  • 4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.]dodecane (caryophyllene oxide)
  • 4theta,6theta,10s)]-thet
  • 5-)xatricyclo[8.2.0.0(4,6))dodecane, 6,,11,11-trimethyl-2-methylene, [1R-(1R*,4R*,6R*,10S*)]-
  • 5-oxatricyclo(8.2.0.0(4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r-(1r*,4
  • 5-oxatricyclo(8.2.0.0(sup4,6))dodecane,4,12,12-trimethyl-9-methylene-,(1r,4r
  • 5-Oxatricyclo(8.2.0.04,6)dodecane, 4,12,12-trimethyl-9-methylene-, (1R,4R,6R,10S)-
  • 5-Oxatricyclo[8.2.0.0(4,6)-]dodecane, 4,12,12-trimethyl-9-methylene-, [1R-(1R*,4R*,6R*,10S*)]-
  • 5-oxatricyclo[8.2.0.04,6]dodecane,,12,12-trimethyl-3-methylene-[1r-
  • 6]dodecane,4,12,12-trimethyl-9-methylene-,[1R-(1R*,4R*,6R*,10S*)]-5-Oxatricyclo[8.2.0.04
  • 6]dodecane,4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0.0[1theta-(1
  • 6r*,10s*))-r
  • beta-Caryophyllene oxide
  • beta-caryophylleneepoxide
  • beta-caryophylleneoxide
  • (-)-Caryophyllene oxide, 95% 10GR
  • CARYLOPHYLLENE OXIDE
  • (-)-CARYOPHYLLENE OXIDE, >= 99.0 % G
  • (-)-Caryophyllene oxide@100 μg/mL in Methanol
  • (-)-Caryophyllene oxide, 95%
  • Caryopyllene oxide
  • Caryophyllene oxide USP/EP/BP
  • β-Caryophyllene Epoxide
  • TIANFUCHEM--1139-30-6--High purity CARYOPHYLLENE OXIDE in stock
  • (-)-Caryophyllene oxide, 95%,
  • DXP 5648
  • DXP5648
  • DXP-5648
  • (-)-beta-Caryophyllene epoxide
  • caryophyleneoxide
  • Caryophyllene epoxide
  • Caryophyllene oxyde
  • (-)-EPOXYCARYOPHYLLENE
  • (-)-CARYOPHYLLENE OXIDE
  • CARYOPHYLLENEPOXID
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