Ethylnitrit

Ethyl nitrite Struktur
109-95-5
CAS-Nr.
109-95-5
Bezeichnung:
Ethylnitrit
Englisch Name:
Ethyl nitrite
Synonyma:
Ethy nitrite;nitrousether;ETHYL NITRITE;hyponitrousether;nitrousethylether;Nitrosyl ethoxide;sweetspiritofnitre;sweetspiritofniter;Nitrous acid ethyl;spiritofethylnitrite
CBNumber:
CB8191069
Summenformel:
C2H5NO2
Molgewicht:
75.07
MOL-Datei:
109-95-5.mol

Ethylnitrit Eigenschaften

Siedepunkt:
bp 17°
Dichte
0.792 g/mL at 25 °C
FEMA 
2446 | ETHYL NITRITE
Brechungsindex
n20/D 1.36
Flammpunkt:
59 °F
storage temp. 
2-8°C
Geruch (Odor)
Aromatic; ethereal; characteristic.
Geruchsart
ethereal
Merck 
3831
LogP
1.04
CAS Datenbank
109-95-5(CAS DataBase Reference)
NIST chemische Informationen
Nitrous acid, ethyl ester(109-95-5)
EPA chemische Informationen
Ethyl nitrite (109-95-5)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher F,Xn,E
R-Sätze: 11-20/21/22-2
S-Sätze: 7-16-35
RIDADR  UN 1194 3/PG 1
RTECS-Nr. RA0810000
HazardClass  3.1
PackingGroup  I
Giftige Stoffe Daten 109-95-5(Hazardous Substances Data)
Toxizität cat,LC,inhalation,> 200mg/m3/15M (200mg/m3),Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 48(1), Pg. 62, 1983.
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H225 Flüssigkeit und Dampf leicht entzündbar. Entzündbare Flüssigkeiten Kategorie 2 Achtung GHS hazard pictogramssrc="/GHS02.jpg" width="20" height="20" /> P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P210 Von Hitze, heißen Oberflächen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P233 Behälter dicht verschlossen halten.
P240 Behälter und zu befüllende Anlage erden.
P241 Explosionsgeschützte [elektrische/Lüftungs-/ Beleuchtungs-/...] Geräte verwenden.
P242 Nur funkenfreies Werkzeug verwenden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Ethylnitrit Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R11:Leichtentzündlich.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
R2:Durch Schlag, Reibung, Feuer oder andere Zündquellen explosionsgefährlich.

S-Sätze Betriebsanweisung:

S7:Behälter dicht geschlossen halten.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S35:Abfälle und Behälter müssen in gesicherter Weise beseitigt werden.

Beschreibung

The chemical compound ethyl nitrite is an alkyl nitrite. It may be prepared from ethanol
Ethyl nitrite is the main ingredient in a traditional ethanol-based South African remedy for colds and flu known as Witdulsies and sold in pharmacies. It is known as a traditional Afrikaans remedy and may have Dutch roots, as the same remedy is apparently made by the Germano-Dutch Amish people in the USA. However FDA has blocked over-the-counter sales of this same remedy, known in the USA as sweet nitrite or sweet spirit of nitre since 1980 .

Chemische Eigenschaften

Ethyl nitrite has a characteristic ether-like odor.

Verwenden

Ethyl Nitrite is an S-nitrosylating agent that improve tissue oxygenation in humans and sheep at normoxia and at reduced fraction of inspired oxygen during microvasculature. Ethyl Nitrite is also used as a therapeutic gas utilized in neonatal Intensive Care Unit.

synthetische

From sodium nitrite in aqueous solution by displacing the acid with H2SO4 in the presence of ethyl alcohol; it forms azeotropic mixtures with isopentane (85%), amyl bromide (40%) and carbon disulfide (96%).

Weltgesundheitsorganisation (WHO)

Ethyl nitrite was formerly available in over-the-counter preparations for use as a diaphoretic, a diuretic and an intestinal antispasmodic. In the 1970s its use was associated with cases of methaemoglobinaemia, some of which were fatal. This led to its withdrawal in 1980 by the United States Food and Drug Administration. WHO has no information regarding its current availability in pharmaceutical preparations.

Allgemeine Beschreibung

A clear colorless to yellow liquid with a pleasant odor. Flammable over a wide range of vapor-air concentrations. Flash point -31°F. Less dense than water and insoluble in water. Vapors are heavier than air and narcotic in high concentrations. Produces toxic oxides of nitrogen during combustion.

Air & Water Reaktionen

Highly flammable. Vapors may ignite spontaneously and the reaction may reach explosive violence. Insoluble in water. Decomposes in water.

Reaktivität anzeigen

ETHYL NITRITE is a powerful oxidizing agent. Highly dangerous in contact with acid or acid fumes. Dangerous when heated. Decomposes spontaneously at 194°F. Decomposed by light.

Hazard

Highly flammable, dangerous, explodes.

Health Hazard

Inhalation or ingestion causes headache, increased pulse rate, decreased blood pressure, and unconsciousness. Contact with liquid irritates eyes and skin.

Chemische Reaktivität

Reactivity with Water: No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable if stored in a cool place and not exposed to strong light; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Sicherheitsprofil

Poison by inhalation and ingestion. Narcotic in high concentrations. Lowers blood pressure. Methemoglobinemia has been reported. A very dangerous fire and severe explosion hazard when exposed to heat or flame. A powerful oxidizer. May explode when heated above 90℃. Highly dangerous when heated to decomposition or on contact with acid or acid fumes. To fight fire, use foam, CO2, dry chemical, or water spray. When heated to decomposition it emits toxic fumes of NOx. See also NITRITES and ETHERS.

Ethylnitrit Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

109-95-5(Ethylnitrit)Verwandte Suche:


  • ethylesterkyselinydusite
  • ethylnitrite,solution
  • hyponitrousether
  • nitrousether
  • nitrousethylether
  • spiritofethylnitrite
  • sweetspiritofniter
  • sweetspiritofnitre
  • NITROUS ACID ETHYL ESTER
  • Nitrosyl ethoxide
  • Ethy nitrite
  • ETHYL NITRITE
  • ETHYL NITRITE-ETHANOL
  • ETHYL NITRITE, 10-20 WT. % SOLUTION IN E THYL ALCOHOL
  • Ethyl Nitrite (ca. 15% in Ethanol, ca. 1.6mol/L)
  • NITROUS ETHER 15% IN ETHANOL
  • Nitrous acid ethyl
  • Ethyl nitrite,alcoholic solution
  • Ethylnitrite.sol(inethanol)
  • 10% Ethyl Nitrite-Ethanol Solution
  • EthylNitrite(ca.15%inEthanol,ca.1.6mol/L)>
  • Nicorandil Impurity 25
  • Nicorandil Impurity 15 (10-20% solution in EtOH)
  • 109-95-5
  • C2H5ONO
  • CH3CH2ONO
  • Nitrogen Compounds
  • Organic Building Blocks
  • Organic Nitrates/Nitrites
  • Building Blocks
  • Nitrogen Compounds
  • Organic Building Blocks
  • Organic Nitrates/Nitrites
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