Zinkfluorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R37/38:Reizt die Atmungsorgane und die Haut.
R41:Gefahr ernster Augenschäden.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S39:Schutzbrille/Gesichtsschutz tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
Beschreibung
Zinc fluoride (ZnF2) is an inorganic chemical compound. Zinc fluoride is used in the fluorination of organic compounds, in the manufacturing of phosphors for fluorescent lights, in preserving wood, in electroplating baths, in galvanizing steel, and in ceramic manufacturing for glazes and enamels. It is also used as a termite repellent, in pharmaceuticals (e.g. the inhibition of dentin demineralization and collagen degradation), as a flux for welding and soldering (e.g. aluminum).
Chemische Eigenschaften
White powder. Soluble in hot acids; slightly soluble
in water; insoluble in alcohol.
Physikalische Eigenschaften
Anhydrous zinc fluoride is a white hygroscopic solid; tetragonal needles; density 4.9 g/cm
3; melts at 872°C; vaporizes at 1,500°C; vapor pressure 1 torr at 1,243°C and 5 torr at 1,328°C; practically insoluble in water, 5.2 mg/L; sparingly soluble in HCl, HNO
3 and ammonia solution
The hydrated salt, ZnF
2?4H
2O, is a white crystalline solid; rhombohedral crystals; density 2.30 g/cm3; loses water of crystallization at 100°C; sparinglysoluble in water, about 1.52 g/100mL at 20°C.
Verwenden
Zinc fluoride is a white crystalline powder, used in the manufacture of phosphors for fluorescent lights. It also is used in electroplating baths, in preservation of wood, in glazes and enamels for ceramics, and in fluorination reactions of organics.
synthetische
Zinc fluoride may be prepared by heating zinc hydroxide or zinc carbonate with hydrogen fluoride:
Zn(OH)2 + 2HF → ZnF2 + 2H2O
ZnCO3 + 2HF → ZnF2 + CO2 + H2O
Also, it can be precipitated by adding a solution of sodium fluoride to that of zinc acetate:
(CH3COO)2Zn + 2NaF → ZnF2 + 2CH3COONa
Hazard
Toxic material.
Sicherheitsprofil
Poison by
subcutaneous route. Can react violently with
potassium. A fluorination agent. When
heated to decomposition it emits toxic
fumes of F and ZnO. See also
FLUORIDES and ZINC COMPOUNDS.
läuterung methode
A possible impurity is H2O which can be removed by heating at 100o or by heating to 800o in a dry atmosphere. Heating in the presence of NH4F produces larger crystals. It is sparingly soluble in H2O (1.51g/100mL) but more soluble in HCl, HNO3 and NH4OH. It can be stored in glass bottles. [Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 242 1963.]
Einzelnachweise
[1] http://www.npi.gov.au/resource/zinc-and-compounds
[2] https://hazmap.nlm.nih.gov/category-details?id=7782&table=copytblagents
[3] Patent EP 0001677 A1: Flux for soft soldering of aluminum, a fluxed solder composition containing said flux and a method of soft soldering aluminum using said flux
Zinkfluorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
