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Schwefelhexafluorid Produkt Beschreibung

Sulfur hexafluoride Struktur
2551-62-4
CAS-Nr.
2551-62-4
Bezeichnung:
Schwefelhexafluorid
Englisch Name:
Sulfur hexafluoride
Synonyma:
SF6;Elegas;Esaflon;OC-6-11;SULFURHEXAFLORIDE;Hexafluorosulphane;SULFUR HEXAFLUORIDE;sulfurfluoride(sf6);SULFUR HEXAFLOURIDE;Schwefelhexafluorid
CBNumber:
CB7724783
Summenformel:
F6S
Molgewicht:
146.06
MOL-Datei:
2551-62-4.mol

Schwefelhexafluorid Eigenschaften

Schmelzpunkt:
−50 °C(lit.)
Siedepunkt:
−64 °C1 mm Hg(lit.)
Dichte
6.602
Dampfdichte
5.11 (vs air)
Dampfdruck
22 mm Hg ( 21.1 °C)
Aggregatzustand
colorless gas
Wasserlöslichkeit
slightly
Merck 
13,9063
Stabilität:
Stable. Non-flammable. Explodes on contact with disilane. Reacts with sodium.
CAS Datenbank
2551-62-4(CAS DataBase Reference)
NIST chemische Informationen
Sulfur hexafluoride(2551-62-4)
EPA chemische Informationen
Sulfur fluoride (SF6), (OC-6-11)-(2551-62-4)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 37
S-Sätze: 38
RIDADR  UN 1080 2.2
WGK Germany  -
RTECS-Nr. WS4900000
Hazard Note  Irritant
HazardClass  2.2
Giftige Stoffe Daten 2551-62-4(Hazardous Substances Data)
Bildanzeige (GHS)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H280 Enthält Gas unter Druck; kann bei Erwärmung explodieren. Gase unter Druck verflüssigtes Gas Warnung P410+P403
Sicherheit
P410 Vor Sonnenbestrahlung schützen.

Schwefelhexafluorid Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

GERUCHLOSES, FARBLOSES, KOMPRIMIERTES FLüSSIGGAS.

PHYSIKALISCHE GEFAHREN

Das Gas ist schwerer als Luft. Es kann sich in tiefer gelegenen Bereichen sammeln und den Luftsauerstoff verdrängen.

CHEMISCHE GEFAHREN

Zersetzung beim Erhitzen über 500°C unter Bildung giftiger und ätzender Rauche mit Schwefeloxiden und Fluorverbindungen.

ARBEITSPLATZGRENZWERTE

TLV: 1000 ppm (als TWA); (ACGIH 2005).
MAK: 1000 ppm, 6100 mg/m? Spitzenbegrenzung: überschreitungsfaktor II(8); Schwangerschaft: Gruppe D (DFG 2006).

AUFNAHMEWEGE

Aufnahme in den Körper durch Inhalation.

INHALATIONSGEFAHREN

Eine gesundheitsschädliche Konzentration des Gases in der Luft wird beim Entweichen aus dem Behälter sehr schnell erreicht.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Schnelle Verdampfung kann zu Erfrierungen führen.

LECKAGE

Gefahrenbereich verlassen! Belüftung. Wasserstrahl NIEMALS auf die Flüssigkeit richten. Persönliche Schutzausrüstung: Chemikalienschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.

R-Sätze Betriebsanweisung:

R37:Reizt die Atmungsorgane.

S-Sätze Betriebsanweisung:

S38:Bei unzureichender Belüftung Atemschutzgerät anlegen.

Chemische Eigenschaften

Chemical properties of sulfur hexafluoride are very stable. And compared to selenium hexafluoride, the hydrolysis rate of sulfur hexafluoride is extremely low, this is due to the small radius sulfur atom, which resulting in six fluorine atoms form a larger steric hindrance around. However, the fluorine atom radius is not big, so the repulsive force between the six fluorine atoms is not too large, S-F bond is not easy to dissociate. Enthalpy of formation of sulfur hexafluoride is-1220 kJ/mol, but enthalpy of formation of sulfur hexafluoride is-74 kJ/mol. Thus, the radius of fluorine atom and sulfur atom radius cause the very stable of sulfur hexafluoride molecule together---the molecules themselves are difficult to disconnect bond and break down and the attack group is difficult to approach to the central atom, in the thermodynamics and kinetics, they are both stable. Studies have said sulfur hexafluoride can be stably present in the atmosphere for thousands of years.

Verwenden

Sulfur hexafluoride is used extensively as a gaseous dielectric in various kinds of electrical power equipment, such as switchgear, transformers, condensers, and circuit breakers. It has also been used as a dielectric at microwave frequencies and as an insulating medium for the power supplies of high-voltage machines.
Sulfur hexafluoride is also gaining use in nonelectrical applications, including blanketing of molten magnesium, leak detection, and plasma etching in the semiconductor industry. Sulfur hexafluoride also has some limited medical applications.

Trademarks

SonoVue (for the microbubble formulation) (Ausimont).

Reaktivität anzeigen

This substance undergoes chemical reactions only under relatively severe circumstances. They are resistant to ignition, although they may become flammable at very high temperatures. They may be resistant to oxidation reduction, except in the most severe conditions. These materials may be nontoxic. They can asphyxiate. Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980].

Hazard

Asphyxiant.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

Brandgefahr

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

Sicherheitsprofil

This material is chemically inert in the pure state and is considered to be physiologcally inert as well. However, as it is ordinarily obtainable, it can contain variable quantities of the lowsulfur fluorides. Some of these are toxic, very reactive chemically, and corrosive in nature. These materials can hydrolyze on contact with water to yield hydrogen fluoride, which is highly toxic and very corrosive. In high concentrations and when pure it may act as a simple asphyxiant. Incompatible with disilane. Vigorous reaction with disilane. May explode. When heated to decomposition emits highly toxic fumes of Fand SOx.

mögliche Exposition

May contain highly toxic sulfur pentafluoride as an impurity. SF6 is used in various electric power applications as a gaseous dielectric or insulator. The most extensive use is in high-voltage transformers. SF6 is also used in waveguides, linear particle accelerators; Van de Graaff generators; chemically pumped continuous-wave lasers; transmission lines; and power distribution substations. Nonelectrical applications include use as a protective atmosphere for casting of magnesium alloys and use as a leak detector or in tracing moving air masses. Several sources note that vitreous substitution of SF6 in owl monkeys results in a greater ocular vascular permeability than that caused by saline. This implies that SF6 could have an important use in retinal surgery.

Versand/Shipping

UN1080 Sulfur hexafluoride, Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas. Cylinders must be transported in a secure upright position, in a wellventilated truck. Protect cylinder and labels from physical damage. The owner of the compressed gas cylinder is the only entity allowed by federal law (49CFR) to transport and refill them. It is a violation of transportation regulations to refill compressed gas cylinders without the express written permission of the owner.

Inkompatibilitäten

May contain impurities that cause it to hydrolyze on contact with water, forming corrosive and toxic hydrogen fluoride. Vigorous reaction with disilane.

Waste disposal

Return refillable compressed gas cylinders to supplier. Seal unused cylinders and return to suppliers.

Chemische Eigenschaften

Sulfur pentafluoride and sulfur tetrafluoride are classified by OSHA as highly hazardous chemicals under its Process Safety Management Standard and as toxic industrial chemicals on the basis of their highly toxic nature and production in large quantities (29 CFR 1910).

Schwefelhexafluorid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Schwefelhexafluorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 87)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21759 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20672 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Hangzhou FandaChem Co.,Ltd.
0086 158 5814 5714 (Mobile; WhatsApp; Telegram)
+86-571-56059825 fandachem@gmail.com CHINA 2840 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 27142 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23964 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28237 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 sales@guangaobio.com CHINA 23049 58
Shandong chuangyingchemical Co., Ltd.
13156170209
sale@chuangyingchem.com CHINA 4419 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

2551-62-4(Schwefelhexafluorid)Verwandte Suche:


  • sulfurfluoride(sf6)
  • sulfurhexafluoride,highpurity
  • LEAK DETECTION STANDARD LD-1
  • SULPHUR HEXAFLUORIDE
  • SULFURYL HEXAFLUORIDE
  • SULFUR HEXAFLUORIDE
  • sulfur hexafluoride cyl. with 4.75 kg (~net)
  • Sulphurhexafluoride2
  • SULFUR HEXAFLOURIDE
  • SULFUR HEXAFLUORIDE, 99.75+%
  • Sulfur fluoride (SF6), (OC-6-11)-
  • Sulphur hexafluoride 99.9%
  • Schwefelhexafluorid
  • SULFURHEXAFLORIDE
  • Sulfur hexafluoruides
  • Hexafluorosulfur(VI)
  • Sulfur(VI)hexafluoride
  • SF6 injecting reagent
  • Hexafluorosulphane
  • Electronic Sulfur hexafluoride
  • Sulphur hexafluoride 99%
  • Sulfur Hexafluoride(SF6) electronic grade
  • (OC-6-11)-Sulfurfluoride
  • (oc-6-11)-sulfurfluoride(sf6
  • Elegas
  • Esaflon
  • Hexafluorure de soufre
  • hexafluoruredesoufre
  • hexafluoruredesoufre(french)
  • OC-6-11
  • Schwefelhcsafluorid
  • SF6
  • 2551-62-4
  • Synthetic Reagents
  • Compressed and Liquefied Gases
  • Inorganics
  • Inorganic Fluorides
  • Vitamin Ingredients
  • Chemical Synthesis
  • Compressed and Liquefied Gases
  • Synthetic Reagents
  • -
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