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Resmethrin (ISO) Produkt Beschreibung

RESMETHRIN Struktur
10453-86-8
CAS-Nr.
10453-86-8
Bezeichnung:
Resmethrin (ISO)
Englisch Name:
RESMETHRIN
Synonyma:
Seco;ari-b;Syntox;xylate;For-syn;Vectrin;CHRYSON;Scourge;SBP 1383;OMS-1206
CBNumber:
CB9311222
Summenformel:
C22H26O3
Molgewicht:
338.44
MOL-Datei:
10453-86-8.mol

Resmethrin (ISO) Eigenschaften

Schmelzpunkt:
56.5℃
Siedepunkt:
bp >180° (dec)
Dichte
0.96 g/cm3
Dampfdruck
﹤l×10-5 Pa (25 °C)
Brechungsindex
1.5287 (20℃)
Flammpunkt:
closed cup: 264.2°F (129°C)
storage temp. 
0-6°C
Wasserlöslichkeit
0.038 mg l-1 (25 °C)
Aggregatzustand
neat
BRN 
1626510
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xn,N
R-Sätze: 22-50/53
S-Sätze: 60/61-61-60
RIDADR  3082
WGK Germany  3
RTECS-Nr. GZ1310000
HazardClass  9
PackingGroup  III
HS Code  29321900
Toxizität LC50 (96 hr) in rainbow trout, bluegill sunfish (mg/l): 3.14, 7.2 (Rand)
Bildanzeige (GHS)
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung P264, P270, P301+P312, P330, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 1 Warnung P273, P391, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P391 Verschüttete Mengen aufnehmen.
P501 Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Resmethrin (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSER WACHSARTIGER FESTSTOFF IN VERSCHIEDENEN FORMEN, MIT CHARAKTERISTISCHEM GERUCH.

CHEMISCHE GEFAHREN

Zersetzung beim Erhitzen unter Bildung reizender Rauche.

ARBEITSPLATZGRENZWERTE

TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).

AUFNAHMEWEGE

Aufnahme in den Körper durch Inhalation des Aerosols und durch Verschlucken.

INHALATIONSGEFAHREN

Nur ungenügende Angaben vorhanden über die Geschwindigkeit, mit der eine gesundheitsschädliche Konzentration in der Luft beim Verdampfen bei 20°C erreicht wird.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Augen und die Haut.

LECKAGE

NICHT in die Kanalisation spülen. NICHT in die Umwelt gelangen lassen. Verschüttetes Material in Behältern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgfältig sammeln. An sicheren Ort bringen.

R-Sätze Betriebsanweisung:

R22:Gesundheitsschädlich beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

S-Sätze Betriebsanweisung:

S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.

Chemische Eigenschaften

Off-white to tan waxy solid or colorless crys- tals. Chrysanthemum-like odor. Commercial products may be dissolved in flammable organic solvents

Verwenden

Resmethrin is used to control a wide range of insects in horticultural, household, public health and animal health situations. It has some agricultural use but this is limited. The more active 1Rtrans form has a similar range of uses and is also used in stored grain products.

Allgemeine Beschreibung

Colorless crystals or waxy solid. Insoluble in water. Used as an insecticide.

Air & Water Reaktionen

Insoluble in water.

Reaktivität anzeigen

A pyrethroid derivative.

Landwirtschaftliche Anwendung

Insecticide: Resmethrin is currently used for mosquito control (by aerial application) in the USA, and may can also be used in greenhoused to control white fly. Resmethrin is a synthetic Type I pyrethroid insecticide registered for control of insects in residential, commercial and industrial settings, and in animal living areas. Resmethrin is also registered for use in food-handling establishments and as a restricted use pesticide when used in ULV spray to control adult mosquitoes in the interest of public health[83]. Restricted Use Pesticide (RUP) when formulated for use in mosquito abatement and pest control treatments at nonagricultural sites. Restricted due to extreme fish toxicity. Not approved for use in EU countries.

Handelsname

(d-trans-isomer); SBP® 1382 (d-trans-isomer); d-transSBP® 1382 (d-trans-isomer); SBP®-1390; S. B. PENICK 1382®; SCOURGE®; SUN-BUGGER®; SYNTHRIN®; SYNTOX®; VECTRIN®; WHITMIRE® PT-110

mögliche Exposition

Resmethrin is pyrethroid insecticide used for mosquito control (by aerial application) in the USA, and may can also be used in greenhouses to control white fly. Resmethrin is a synthetic Type I pyrethroid insecticide registered for control of insects in residential, commercial, and industrial settings, and in animal living areas. It is also registered for use in food handling estab- lishments and as a restricted use pesticide when used in ULV spray to control adult mosquitoes in the interest of public health . A United States Restricted Use Pesticide (RUP) when formulated for use in mosquito abatement and pest control treatments at nonagricultural sites. Restricted due to extreme fish toxicity.

Stoffwechselwegen

14C-resmethrin are individually administered orally to white leghorn hens, and more than 90% of the radioactivity is eliminated in the excreta within 24 h of treatment. The metabolic routes for both resmethrin isomers arise from ester hydrolysis and oxidation of the hydrolytic products. Some of these metabolites are further conjugated with glucuronic acid, sulfate, or other unidentified compounds before excretion.

Versand/Shipping

UN3352 Pyrethroid pesticide, liquid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material

Degradation

The resmethrins are reasonably stable but they are sensitive to base hydrolysis forming the chrysanthemic acid isomers (2) and 5-benzyl-3- furylmethanol (3). They are also sensitive to oxidation and to photodecomposition. Photo-oxidation involves degradation of the furan ring to yield a cyclic ozonide peroxide by addition of oxygen across the unsaturated system forming the hydroxylactone derivative (4), the benzyloxylactone derivative (5) and the hydroxycyclopentenolone (6) (Ueda et al., 1974). These chemical and photochemical reactions are shown in Scheme 1.
Degradation also occurs in the acid moiety by reactions analogous to those described under phenothrin, for example, oxidation at the isobutylene substituent to afford a variety of alcohols, aldehydes and carboxylic acids. These two sites of weakness in the resmethrin molecule result in considerable photo-instability (though they are more stable than the pyrethrins) and to a complex mixture of degradation products.

Inkompatibilitäten

Decomposed by air, light, alkaline media, and temperatures .175℃. May react violently with strong oxidizers, bromine, 90% hydrogen peroxide, phos- phorus trichloride, silver powders or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate.

Waste disposal

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165. Follow recommendations for the disposal of pesticides and pesticide containers . Bury in noncrop land away from water. It would be better to mix the prod- uct with lime. Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amount of combustible material. Recommendable methods: Hydrolysis, landfill, incineration, and open burning. Not recommendable method: Discharge to sewer. Mix with saw- dust and burn at a remote place .

Resmethrin (ISO) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Resmethrin (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 51)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
BOC Sciences
1-631-619-7922
1-631-614-7828 inquiry@bocsci.com United States 20115 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
BEST-REAGENT 400-1166-196 18981987031
028-84555506 QQ:800101999 cdhxsj@163.com China 9900 57
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 ; 028-86676798 ; 028-86757656
028-86757656 aikeshiji@163.com China 9755 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 24986 65
Nanjing Sunlida Biological Technology Co., Ltd. 025-58378339;025-57798810
025-57019371 sales@sunlidabio.com China 3818 55
Shanghai JONLN Reagent Co., Ltd. 400-0066-400;021-60496031
021-55660885 shjlsw@163.com China 10092 55
TianJin Alta Scientific Co., Ltd. +86-022-6537-8550
+86-022-2532-9655 contact@altascientific.com China 2775 58
Alta Scientific Co., Ltd. (0086) 22-6537-8550; 185-2256-9193; 185-2256-9194
(0086) 22-2532-9655 contact@altascientific.com China 8312 55

10453-86-8(Resmethrin (ISO))Verwandte Suche:


  • (5-Benzyl-3-furyl)methyl cis,trans-2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate
  • resmethrin (bsi,iso,ansi,esa,jmaf)
  • RESMETHRIN STANDARD
  • resmethrin (ISO) 5-benzyl-3-furylmethyl (±)-cis-trans-chrysanthemate
  • 5-Benzyl-3-furylmethyl-dl-cis,trans crysanthemate
  • Resmethrin 250mg [10453-86-8]
  • [5-(Phenylmethyl)-3-furanyl]methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
  • dl-cis,trans-[(5-Benzyl-3-furyl)methyl]chrysanthemumate
  • SBP 1383
  • Seco
  • Resmethrin 0.1
  • (5-(phenylmethyl)-3-furanyl)methyl2,2-dimethyl-3-(2-methyl-1-propenyl)cyclop
  • ethyl)-3-furanyl]methylester
  • For-syn
  • lopropanecarboxylate
  • -methylpropenyl)cyclopropanecarboxylate
  • NSC 195022
  • nsc195022
  • OMS-1206
  • opanecarboxylate
  • Penick 1382
  • Penick SBP 1382
  • penick1382
  • penncapthrin
  • Premgard
  • Sun-Bugger
  • Sun-Bugger 4
  • Syntox
  • uryl)methylester
  • Vectrin
  • Whitmire PT-110
  • xylate
  • 5-BENZOYL-3-FURYLMETHYL (1RS)-CIS-TRANS-CHRYSANTHEMATE
  • 5-BENZYL-3-FURYLMETHYL (1R,S)-CIS,TRANS-CHRYSANTHEMATE
  • (5-BENZYL-3-FURYL)METHYL-2,2-DIMETHYL-3-(2-METHYLPROPENYL) CYCLOPROPANECARBOXYLATE
  • (5-BENZYL-3-FURYL)METHYL-2,2-DIMETHYL-3-(2-METHYLPROPHENYL) CYCLOPROPANECARBOXYLATE
  • FMC 17370
  • CHRYSRON(R)
  • CHRYSON
  • BENZOFUROLINE
  • SBP 1382
  • SYNTHRIN
  • SYNTHRIN(R)
  • RESMETHRIN
  • NIA 17370
  • NRDC 104
  • 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid [5-(phenylmethyl)-3-furanyl]methyl ester
  • Resmethrinl
  • RESMETHRIN, 250MG, NEAT
  • RESMETHRIN PESTANAL, 250 MG
  • Ethyl 3-Oxo-4-aza-5&alpha
  • (5-(phenylmethyl)-3-furanyl)methyl2,2-dimethyl-3-furylmethyl2,2-dimethyl-3-(2
  • (5-(phenylmethyl)-3-furanyl)methylester
  • (5-Benzyl-3-furyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
  • (5-Benzyl-3-furyl)methyl chrysanthemate
  • (5-benzyl-3-furyl)methyl(1rs)-cis,trans-2,2-dimethyl-3-(2-methylpropenyl)cyc
  • (5-benzyl-3-furyl)methyl-2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarbo
  • (5-benzyl-3-furyl)methyl-2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxy
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