S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate

S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate Struktur
78-53-5
CAS-Nr.
78-53-5
Englisch Name:
S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate
Synonyma:
DSDP;R-5158;Amiton;Inferno;Metramac;Brn 1785674;Amiton [bsi];Chipman 6200;Caswell no. 333d;3734-97-2 (Oxalate[1:1])
CBNumber:
CB9852206
Summenformel:
C10H24NO3PS
Molgewicht:
269.34
MOL-Datei:
78-53-5.mol

S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate Eigenschaften

Schmelzpunkt:
25°C
Siedepunkt:
bp0.01 76°; bp0.2 110°
Dichte
1.070±0.06 g/cm3(Predicted)
Brechungsindex
nD27 1.4655
Aggregatzustand
liquid
pka
9.39±0.25(Predicted)
EPA chemische Informationen
O,O-Diethyl S-(2-(diethylamino)ethyl) phosphorothioate (78-53-5)

Sicherheit

RIDADR  3018
HazardClass  6.1(a)
PackingGroup  I
Giftige Stoffe Daten 78-53-5(Hazardous Substances Data)
Toxizität LD50 orally in rats: 5.4 mg/kg (Frawley)

S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Amiton is a liquid organophosphate.

Verwenden

Insecticide.

Allgemeine Beschreibung

Liquid. Used as an acaricide and insecticide.

Reaktivität anzeigen

Organothiophosphates, such as S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Hazard

Cholinesterase inhibitor. Use may be restricted.

Health Hazard

S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate is highly toxic orally. It is a cholinesterase inhibitor.

Brandgefahr

When heated to decomposition, can emit toxic fumes of oxides of nitrogen, phosphorus, and sulfur. (Non-Specific -- Organophosphorus Pesticide, Liquid, n.o.s.) Container may explode in heat of fire. Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases. Runoff from fire control or dilution water may cause pollution. Avoid extreme heat.

mögliche Exposition

Amiton is used as an acaricide and an insecticide; exposure may occur in manufacture and in application and use. VG has been used as a military nerve agent.

Versand/Shipping

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous material.

läuterung methode

Recrystallise it from isopropanol/diethyl ether. [Ailman & Magee in Organo Phosphorus Compound (Kosolapoff & Maier eds) Wiley Vol 7 pp 487-871 1976.] Diethylmethylsilane [760 -32 -7] M 102.3, b 78.4o/760mm, 77.2 -77.6o/atm, d 4 0.71. Fractionally distil it through a ca 20-plate column, and the fraction boiling within a range of less than 0.5o is collected. It is a flammable irritating liquid. [Price J Am Chem Soc 69 2600 1947, Beilstein 4 III 1847.]

Inkompatibilitäten

Contact with strong oxidizers may cause release of toxic phosphorus oxides. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Organophosphates, in the presence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

Waste disposal

Use a licensed professional waste disposal service to dispose of this material. All federal, state, and local environmental regulations must be observed. High-temperature incineration. Hydrolysis may also be used. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


  • O,O-diethyl S-(2-diethylaminoethyl)phosphorothioate
  • O,O-DIETHYL-5-[2-(DIETHYLAMINO)ETHYL]PHOSPHONOTHIOATE
  • Amiton: (O,O-Diethyl-S-(2-diethylaminoethyl) thiophosphate)
  • DSDP
  • Inferno
  • Metramac
  • Phosphorothioic acid S-(2-diethylaminoethyl) O,O-diethyl
  • R-5158
  • O,O-DIETHYL-S-[2-(DIETHYLAMINO)ETHYL]PHOSPHOROTHIOLATE
  • (2-Diethylamino)ethylphosphorothioic acid o,o-diethyl ester
  • 3734-97-2 (Oxalate[1:1])
  • Amiton [bsi]
  • Brn 1785674
  • Caswell no. 333d
  • Chipman 6200
  • Diethyl S-2-diethylaminoethyl phosphorothioate
  • Amiton
  • S-[2-(Diethylamino)ethyl]O,O-diethylphosphorothioate
  • PJISLFCKHOHLLP-UHFFFAOYSA-N
  • Phosphorothioic acid, S-[2-(diethylamino)ethyl] O,O-diethyl ester
  • 78-53-5
  • C10H24NO3PS
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