ChemicalBook >> CAS DataBase List >>Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
- CAS No.
- 199684-47-4
- Chemical Name:
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
- Synonyms
- (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2];(R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2];[NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3];[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3];-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R);Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II);DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((R);Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
- CBNumber:
- CB01181085
- Molecular Formula:
- C90H76Cl5NP4Ru2
- Molecular Weight:
- 1674.89
- MDL Number:
- MFCD09753033
- MOL File:
- 199684-47-4.mol
Last updated:2023-06-08 17:06:34
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Properties
Melting point | >100°C |
---|---|
storage temp. | 2-8°C |
form | Powder |
color | orange |
Sensitive | air sensitive |
CAS DataBase Reference | 199684-47-4 |
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 692433 | (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2] | 199684-47-4 | 100mg | $36.8 | 2024-03-01 | Buy |
Sigma-Aldrich | 692433 | (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2] | 199684-47-4 | 500mg | $123 | 2023-06-20 | Buy |
TCI Chemical | N1015 | [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3] | 199684-47-4 | 200mg | $43 | 2024-03-01 | Buy |
TCI Chemical | N1015 | [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3] | 199684-47-4 | 1g | $140 | 2024-03-01 | Buy |
Strem Chemicals | 44-0510 | Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3] | 199684-47-4 | 250mg | $53 | 2024-03-01 | Buy |
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Uses,Production
Reaction
- (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
- Useful ligand in asymmetric Heck processes.
- Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
- Ligand employed in rhodium-catalyzed 1,4-additions to enones.
- Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
- Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
- Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
- Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
- Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
- Ligand employed in palladium-catalyzed synthesis of chiral allenes.
- Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
- Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
- Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
- Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
- Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
Uses
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Suppliers
Global( 33)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6116 | 58 |
Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 10991 | 58 |
J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44700 | 61 |
Shanghai Incat Chemtech Co.,Ltd. | 021-57603038 13601791340 | 307593986@qq.com | China | 475 | 58 |
TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28398 | 80 |
TCI Europe | 320-37350700 | sales@tcieurope.eu | Europe | 23680 | 75 |
TCI AMERICA | 800-4238616 | sales@tciamerica.com | Americas | 23662 | 75 |
Beijing Guofang Dingsheng Technology Co., Ltd. | 18610472091 18610472091 | gfdskj@163.com | China | 494 | 58 |
Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3]
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
(R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II)
[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]
[NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3]
-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R)
DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((R)
(R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]
Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]
199684-47-4
C88H64Cl5P4Ru2C2H7NH
CH32NH2C88H64Cl5P4Ru2
C90H71Cl5NP4Ru2
C90H72Cl5NP4Ru2
Ru