SLAP 5-TMS

SLAP 5-TMS structure

CAS No.: 2084112-39-8

Chemical Name:: SLAP 5-TMS

Synonyms: SLAP 5-TMS TM;SLAP 5-TMS TM >=95%;Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]-

CBNumber:: CB03384635

Molecular Formula:: C9H25NSSi2

Molecular Weight:: 235.54

MDL Number:

MOL File:: 2084112-39-8.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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SLAP 5-TMS Properties

Boiling point	253.6±40.0 °C(Predicted)
Density	0.9126
storage temp.	2-8°C
pka	9.30±0.10(Predicted)
form	suspension

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02
Signal word	Danger
Hazard statements	H225
Precautionary statements	P210-P370+P378-P403+P235
RIDADR	UN 1993BE 3 / PGII

SLAP 5-TMS price More Price(1)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	900815	SLAP 5-TMS TM ≥95%	2084112-39-8	500mg	$109	2023-06-20	Buy

Product number	Packaging	Price	Buy
900815	500mg	$109	Buy

SLAP 5-TMS Chemical Properties,Uses,Production

Uses

When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF₆ (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃ (633305) and Cu(OTf)₂ (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

SLAP 5-TMS Preparation Products And Raw materials

Raw materials

Preparation Products

SLAP 5-TMS Suppliers

Global( 3)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80
Energy Chemical	021-58432009 400-005-6266	marketing1@energy-chemical.com	China	44894	58

Supplier	Advantage
Sigma-Aldrich	80
Energy Chemical	58

SLAP 5-TMS TM >=95% SLAP 5-TMS TM Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]- 2084112-39-8 C9H25NSSi2