SLAP 5-TMS
- CAS No.
- 2084112-39-8
- Chemical Name:
- SLAP 5-TMS
- Synonyms
- SLAP 5-TMS TM;SLAP 5-TMS TM >=95%;Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]-
- CBNumber:
- CB03384635
- Molecular Formula:
- C9H25NSSi2
- Molecular Weight:
- 235.54
- MDL Number:
- MOL File:
- 2084112-39-8.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02 |
---|---|
Signal word | Danger |
Hazard statements | H225 |
Precautionary statements | P210-P370+P378-P403+P235 |
RIDADR | UN 1993BE 3 / PGII |
SLAP 5-TMS price More Price(1)
SLAP 5-TMS Chemical Properties,Uses,Production
Uses
When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.
SLAP 5-TMS Preparation Products And Raw materials
Raw materials
Preparation Products
SLAP 5-TMS Suppliers
Global( 3)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
Energy Chemical | 021-58432009 400-005-6266 | marketing1@energy-chemical.com | China | 44843 | 58 |
Supplier | Advantage |
---|---|
Sigma-Aldrich | 80 |
Energy Chemical | 58 |
SLAP 5-TMS TM >=95%
SLAP 5-TMS TM
Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]-
2084112-39-8
C9H25NSSi2