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ChemicalBook >> CAS DataBase List >> SLAP 5-TMS

SLAP 5-TMS

SLAP 5-TMS price.
  • $109
  • Product name: SLAP 5-TMS
  • CAS: 2084112-39-8
  • MF: C9H25NSSi2
  • MW: 235.54
  • EINECS:
  • MDL Number:
  • Synonyms:SLAP 5-TMS TM >=95%;SLAP 5-TMS TM;Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]-
Price1 Properties Safety Information Description
1 prices
Selected condition：
Brand
  • Sigma-Aldrich
Package
  • 500mg
  • ManufacturerSigma-Aldrich
  • Product number900815
  • Product descriptionSLAP 5-TMS TM ≥95%
  • Packaging500mg
  • Price$109
  • Updated2023-06-20
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 900815 SLAP 5-TMS TM ≥95% 500mg $109 2023-06-20 Buy

Properties

Boiling point :253.6±40.0 °C(Predicted)
Density :0.9126
storage temp. :2-8°C
pka :9.30±0.10(Predicted)
form :suspension

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

Suppliers and manufacturers

Sigma-Aldrich Energy Chemical Merck KGaA